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Electrical resistivity, thermal expansion, and temperature-dependent x-ray diffraction measurements on compounds give mutually consistent evidence for structural phase transitions at 740 K, 550 K, 600 K, and 450 K respectively for R = Y, Sm, Gd, Tb; 0 < x < 0.05. Arguments are given as to why most of the rare-earth - nickel compounds with the 1:2 ratio do not crystallize in the simple cubic Laves phase (C15 type) but show a superstructure of the cubic Laves phase at room temperature and at ambient pressure. This superstructure with the space group and a doubled cell parameter is characterized by ordered vacancies on the R sites. It is shown that the observed structural instabilities result in transitions to the cubic Laves phase (space group ), however with disordered vacancies at high temperatures. High-pressure x-ray powder diffraction experiments show that the phase transition in shifts down to room temperature for a pressure of 27 GPa.

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The lattice dynamics in as‐cast and nanocrystalline thermoelectric Bi2Te3 based p‐type and n‐type material were investigated using inelastic neutron scattering. Generalized densities of phonon states show substantial agreement between the lattice dynamics in as‐cast samples and previous studies. The lattice dynamics in the nanocrystalline materials differ significantly from its as‐cast counterparts in the acoustic phonon regime. In nanocrystalline p‐type and n‐type compounds, the average acoustic phonon group velocity was found to be reduced to 80(5)% and 95(2)% of the value in as‐cast material. It is argued that point‐defect and strain contrast scattering may play an important role for the understanding of lattice thermal conductivity in (nanocrystalline) Bi2Te3 based thermoelectrics beside the observed decrease of sound velocity. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)

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