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The technological and operational properties of polyester resins, unmodified and modified with new freely disperse fillers, were investigated. It was found that modification causes greater dependence of the viscosity on the fatigue load and acceleration of the curing reaction and an increase in the exothermic effect by 2.5-4.5 times. In addition, the strength properties of the modified composites and the water and chemical resistance and impact strength are increased. These finely disperse modifiers are of different colors so that they can act as pigments in concrete structures. Colored facing tiles fabricated from the tmlyester binders have both strength and distinctive decorative and protective properties.Unsaturated polyester resins (usually solutions of unsaturated polyesters in monomers: styrene, dimethacrylates, etc.) are the most common binders in composite materials for different applications (from buttons to yacht and aircraft parts). Their advantage over other binders which can be transformed into cross-linked polymers in polymerization or polycondensation reactions is due to such properties as low viscosity, rapid curing at room and even negative [1] temperatures, good compatibility with mineral fdlers and reinforcing fiber materials, and relatively low cost.Polyester composites containing finely disperse and granular (from sand to fine gravel) fillers and pigments are now widely used. In construction engineering, they are known as po!ymer concretes. Since these materials simulate natural decorative stone (marble, granite, jasper, onyx, malachite) in color, markings, and texture, they are used as decorative-trim tiles, in small architectural structures, sanitary engineering, in fabrication of monuments, etc.Fillers in polyester composites give them thixotropy of the properties (mastic, spackle, adhesive), decrease shrinkage and the exothermic effect in curing, decrease the thermal expansion coefficient, increase the hardness, strength, and heat resistance of the cured material, ensure a given color and markings, and decrease consumption of polymer.There are many types of mineral fillers, but local mineral raw material and industrial wastes are of the greatest technical and economic interest. A special feature of unsaturated polyester resim is their chemisorption interaction with Ca, Mg, Fe, and other oxides [2], which are the basic component in most sedimentary rocks and industrial wastes.We investigated the modifying effect of new finely disperse fillers (both natural and industrial) on the properties of polyester resins and developed composites for construction applications based on them. The fillers were selected for their mineralogical composition and low dispersion, which suggests high surface activity.Natural mineral raw material from the Shatrashansk Deposit in the Republic of Tatarstan was used: glauconite containing more than 30% iron oxide, less than 10% K20, less than 4% MgO, and zeolite-containing rock (ZCR) containing 20-24% zeolites, 20% silica, 51% clay components, and calcites (remainde...

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The paper presents the results of the application of building materials based on thermoplastic (polyvinyl chloride) and thermosetting (urea-formaldehyde) polymers of industrial waste as fillers instead of traditional ones that allow solving resource saving issues. Polyvinyl chloride materials of profile molded products with increased strength by 1.5-2 times were obtained by replacing 50% of the traditional “chemically precipitated chalk” filler with waste from water treatment of thermal power plants. The strength of heat-insulating foams based on urea-formaldehyde resin is increased 3 times by introducing only 0.2 m.p. carbonate water treatment waste per 100 m.p. resins in the binder. The effect is achieved through the implementation of the principle of “condensation” filling of polymer matrices. In polymers of different chemical nature, during filling, the mechanisms of matrix reinforcement associated with the activity of the surface of the filler particles are realized. They are proposed for the practical implementation of the formulation and production technology of profile and sheet materials, as well as heat-insulating foam plastic.

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