The aim of this research was to prepare and analyze suitable microcapsules for the chosen end use—that is, bow-ties. The produced microcapsules were composed of melamine formaldehyde microcapsules with fragrance oils in the core. Regarding the properties, the surface morphology (studied by Scanning electron microscopy (SEM)), thermal properties (measured by Simultaneous Thermal Analysis [STA]), size and size distribution (by SEM and ImageJ software), and release behavior of the microcapsules were analyzed. The microcapsules were further (in two trials) applied with a screen-printing technique to textile materials which were investigated by microscopy (SEM) and tested for thickness, mass per unit area, and crease recovery angle. Finally, the scented bow-ties were designed and a subjective wear test was performed by the participants. According to the results, the prepared microcapsules were undamaged, with a spherical and smooth surface. An impermeable shell enabled the fragrance to be released simply by rupturing the microcapsules. This property was desired, since a stronger release through the permeable shell could be annoying for the wearer. During wear, the fragrance faded, but by rubbing the surface of the bow-tie and consequently rupturing the microcapsules, the release of the fragrance was initiated again, before or after wear.
In the present research, the properties of ultraviolet (UV) visible (daylight invisible) fluorescent coatings modified by the addition of SiO2 and TiO2 nanoparticles were studied. Structural, surface, and mechanical properties and changes in the coatings caused by accelerated ageing were analyzed. The results showed that the addition of nanoparticles caused the changes in unaged and aged printed coatings. Reflectance measurements of modified coatings showed that addition of TiO2 nanoparticles improved the visual effect of the unaged coatings. Furthermore, results have shown that the addition of SiO2 did not diminish the reflectance of the modified coatings after ageing. The results of roughness measurements showed that the addition of SiO2 decreased roughness after the ageing process, probably due to the degradation process indicated by Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR) spectroscopy. The roughness of the coatings with TiO2 nanoparticles was increased after the ageing on the samples with higher concentrations of TiO2 due to the agglomerates of plastisol formed on the surface of the coatings, visible in SEM images. Surface analysis of coatings showed that TiO2 caused an increase in the polarity of the surface coatings. Results of the bending stiffness showed that the addition of the nanoparticles to the coating, especially of SiO2, significantly improved the bending stiffness of the unaged samples.
Polylactic acid (PLA) is one of the most suitable materials for 3D printing. Blending with nanoparticles improves some of its properties, broadening its application possibilities. The article presents a study of composite PLA matrix filaments with added unmodified and lignin/polymerised lignin surface-modified nanofibrillated cellulose (NFC). The influence of untreated and surface-modified NFC on morphological, mechanical, technological, infrared spectroscopic, and dynamic mechanical properties was evaluated for different groups of samples. As determined by the stereo and scanning electron microscopy, the unmodified and surface-modified NFCs with lignin and polymerised lignin were present in the form of plate-shaped agglomerates. The addition of NFC slightly reduced the filaments’ tensile strength, stretchability, and ability to absorb energy, while in contrast, the initial modulus slightly improved. By adding NFC to the PLA matrix, the bending storage modulus (E’) decreased slightly at lower temperatures, especially in the PLA samples with 3 wt% and 5 wt% NFC. When NFC was modified with lignin and polymerised lignin, an increase in E’ was noticed, especially in the glassy state.
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