Cellulose nanocrystals produced by acid hydrolysis of native cellulose form a well-known chiral nematic liquid crystal phase. The mechanism involved in the formation of chirality has been the subject of a vigorous discussion. The pH and concentration dependence of the phase is studied using cellulose nanocrystal droplets within a silicon oil suspension, which allows for convenient real-time microscale manipulation of phase behaviors and properties. We demonstrate the existence of nematic phases at both low and high pH regions consistent with the Stroobants - Lekkerkerker - Odijk theory. Our results confirm electrostatic interactions play a critical role in controlling the strength of the chirality.
Processing 2D sheets into desired structures with high precision is of great importance for fabrication and application of their assemblies. Solution processing of 2D sheets from dilute dispersions is a commonly used method but offers limited control over feature size precision owing to the extreme volume shrinkage. Plastic processing from the solid state is therefore a preferable approach to achieve high precision. However, plastic processing is intrinsically hampered by strong interlayer interactions of the 2D sheet solids. Here, a hydroplastic molding method to shape layered solids of 2D sheets with micrometer‐scale precision under ambient conditions is reported. The dried 2D layered solids are plasticized by intercalated solvents, affording plastic near‐solid compounds that enable local plastic deformation. Such an intercalated solvent‐induced hydroplasticity is found in a broad family of 2D materials, for example graphene, MoS2, and MXene. The hydroplastic molding enables fabrication of complex spatial structures (knurling, origami) and microimprinted tubular structures down to diameters of 390 nm with good fidelity. The method enhances the structural accuracy and enriches the structural diversity of 2D macroassemblies, thus providing a feasible strategy to tune their electrical, optical, and other functional properties.
In this paper, we show that the guided mode resonance can exist in a low-index waveguide layer on top of a high-index substrate. With the help of the interaction of diffraction from a metal grating and total internal reflection effects, we verify that the guided mode can be supported in the low-index SU8 layer on a high-index substrate. Simulation and experiment show the resonant wavelength can be simply manipulated by controlling the geometrical parameters of the metal grating and waveguide layer. This structure extends the possibilities of guided-mode resonance to a broader class of functional materials and may boost its use in applications such as field enhancement, sensing and display.
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