No abstract

No abstract

No abstract

No abstract

Graphene nanosheet (GNS), a single layer of hexagonally arrayed sp 2 -bonded carbon, has attracted increasing attention recently due to its excellent thermal, electrical and mechanical properties. However, manufacturing GNS-filled composites has been very challenging due to the difficulties in large-scale production of GNSs and their dispersion in matrices. GNSs tend to form irreversible agglomerates or even restack to form graphite through van der Waals interactions during the processing of bulk-quantity GNSs, especially in the drying process [1]. Carbon nanotube (CNT), another type of widely studied and applied high-performance carbon-based nanofiller, also has great challenges in composite applications especially due to its expensive production cost. Instead of trying to discover easier large-scale processes for GNSs or lower cost processes for CNTs, an alternative type of carbon-based nanofiller with comparable properties, which can be produced more easily and cost-effectively in large quantities, has also recently been emphasized. Abstract. In this work, an alternative type of carbon-based nanofiller, graphite nanoplatelets (GNPs) with comparable properties, easier and lower-cost production, were used to improve the thermal conductivity of an epoxy. By adding 12 wt% GNPs or 71.7 wt% silicon carbide microparticles (micro-SiCs) to epoxy, the thermal conductivity reached maxima that were respectively 6.3 and 20.7 times that of the epoxy alone. To further improve the thermal conductivity a mixture of the two fillers was utilized. The utilized GNPs are characterized by two-dimensional (2-D) structure with high aspect ratio (~447), which enables GNPs effectively act as heat conductive bridges among 3-D micro-SiCs, thus contributes considerably to the formation of a more efficient 3-D percolating network for heat flow, resulting in higher thermal conductivity with relatively lower filler contents which is important for decreasing the density, viscosity and improving the processability of composites. A thermal conductivity, 26.1 times that of epoxy, was obtained with 7 wt% GNPs + 53 wt% micro-SiCs, thus not only break the bottleneck of further improving the thermal conductivity of epoxy composites but also broaden the applications of GNPs.

No abstract

No abstract

No abstract