Multiple biological structures have demonstrated fog collection abilities, such as beetle backs with bumps and spider silks with periodic spindle-knots and joints. Many Cactaceae species live in arid environments and are extremely drought-tolerant. Here we report that one of the survival systems of the cactus Opuntia microdasys lies in its efficient fog collection system. This unique system is composed of well-distributed clusters of conical spines and trichomes on the cactus stem; each spine contains three integrated parts that have different roles in the fog collection process according to their surface structural features. The gradient of the Laplace pressure, the gradient of the surface-free energy and multi-function integration endow the cactus with an efficient fog collection system. Investigations of the structure–function relationship in this system may help us to design novel materials and devices to collect water from fog with high efficiencies.
Many biological organisms can tune their mechanical properties to adapt to environments in multistable modes, but the current synthetic materials, with bistable states, have a limited ability to alter mechanical stiffness. Here, we constructed programmable organohydrogels with multistable mechanical states by an on-demand modular assembly of noneutectic phase transition components inside microrganogel inclusions. The resultant multiphase organohydrogel exhibits precisely controllable thermo-induced stepwise switching (i.e., triple, quadruple, and quintuple switching) mechanics and a self-healing property. The organohydrogel was introduced into the design of soft-matter machines, yielding a soft gripper with adaptive grasping through stiffness matching with various objects under pneumatic-thermal hybrid actuation. Meanwhile, a programmable adhesion of octopus-inspired robotic tentacles on a wide range of surface morphologies was realized. These results demonstrated the applicability of these organohydrogels in lifelike soft robotics in unconstructed and human body environments.
The combination of photothermal therapy (PTT) and gene therapy (GT) shows great potential to achieve synergistic anti-tumor activity. However, the lack of a controlled release of genes from carriers remains a severe hindrance. Herein, peptide lipid (PL) and sucrose laurate (SL) were used to coat single-walled carbon nanotubes (SCNTs) and multi-walled carbon nanotubes (MCNTs) to form bifunctional delivery systems (denoted SCNT-PS and MCNT-PS, respectively) with excellent temperature-sensitivity and photothermal performance. CNT/siRNA suppressed tumor growth by silencing survivin expression while exhibiting photothermal effects under near-infrared (NIR) light. SCNT-PS/siRNA showed very high anti-tumor activity, resulting in the complete inhibition of some tumors. It was highly efficient for systemic delivery to tumor sites and to facilitate siRNA release owing to the phase transition of the temperature-sensitive lipids, due to PL and SL coating. Thus, SCNT-PS/siRNA is a promising anti-tumor nanocarrier for combined PTT and GT.
Superhydrophobic carbon nanotube (CNT) films have demonstrated many fascinating performances in versatile applications, especially for those involving solid/liquid interfacial processes, because of their ability to affect the material/energy transfer at interfaces. Thus, developing superhydrophobic CNTs has attracted extensive research interests in the past decades, and it could be achieved either by surface coating of low-free energy materials or by constructing micro/nanohierarchical structures via various complicated processes. So far, developing a simple approach to fabricate stable superhydrophobic CNTs remains a challenge because the capillary force induced coalescence frequently happens when interacting with liquid. Herein, drawing inspirations from the lotus leaf, we proposed a simple one-step chemical vapor deposition approach with programmable controlled gas flow to directly fabricate a CNT film with rather stable superhydrophobicity, which can effectively prevent even small water droplets from permeating into the film. The robust superhydrophobicity was attributable to typical lotus-leaf-like micro/nanoscale hierarchical surface structures of the CNT film, where many microscale clusters composed of entangled nanotubes randomly protrude out of the under-layer aligned nanotubes. Consequently, dual-scale air pockets were trapped within each microscale CNT cluster and between, which could largely reduce the liquid/solid interface, leading to a Cassie state. Moreover, the superhydrophobicity of the CNT film showed excellent durability after long time exposure to air and even to corrosive liquids with a wide range of pH values. We envision that the approach developed is advantageous for versatile physicochemical interfacial processes, such as drag reduction, electrochemical catalysis, anti-icing, and biosensors.
Magnetic/antibacterial bifunctional nanoparticles were fabricated through the immobilization of antibacterial N-halamine on silica-coated Fe(3)O(4)-decorated poly(styrene-co-acrylate acid) (PSA) nanoparticles. The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), X-ray diffraction (XRD), energy-dispersive X-ray spectrometry (EDX), Fourier transform infrared (FTIR), and thermogravimetric analysis (TGA). The N-halamine was developed from the precursor 5,5-dimethylhydantoin (DMH) by chlorination treatment, and experimental results showed that the loading amount of DMH on the silica-coated Fe(3)O(4)-decorated poly(styrene-co-acrylate acid) nanoparticles was adjustable. The as-synthesized nanoparticles exhibited superparamagnetic behavior and had a saturation magnetization of 18.93 emu g(-1). Antibacterial tests showed that the resultant nanoparticles displayed enhanced antibacterial activity against both Gram-positive and Gram-negative bacteria compared with their bulk counterparts.
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