Primary processes of photoexcited states in an R-sexithienyl film are investigated by femtosecond transient absorption spectroscopy and picosecond time resolved fluorescence spectroscopy. Four species are observed in the transient absorption measurement. A broad absorption that shows a very rapid relaxation (within a few picoseconds) is ascribed to a singlet Frenkel exciton state. An oscillating structure is also apparent immediately after excitation and is ascribed to the Stark effect induced by a charged species (ion pair state). The latter state decays within 200 ps and is replaced by a different oscillating structure that is due to a thermal effect induced by a dissipation of excess energy. Another band owing to a triplet state appears via a very rapid conversion from a higher singlet exciton state. Fluorescence decay curves are well fitted with lifetimes of the charged state, which indicates that most of the emission is brought about by the charge recombination process, and furthermore, a charge-transfer (CT) emission band that has not been reported is observed.

We study a quasicontinuum system for which there exists a sparse dressed state composed of the ground state and a single state of the true continuum. In general, the loss of population from the ground state to a true continuum via the quasicontinuum is total. In a special case, however, population is trapped in the ground state and the sparse dressed state is replaced by a trapping state containing no contribution from the true continuum.

The optical and structural properties for 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) films deposited on Au-coated substrates at the various growth temperatures by the organic molecular beam deposition (OMBD) method have been studied. The planar PTCDA molecules were oriented almost parallel to the substrate surface in the films deposited at the growth temperature of -160° C. Orientational disorder of the molecular planes occurred especially in the films grown at higher substrate temperatures. These films had basically large anisotropy of refractive indices which were evaluated by the prism attenuated total-reflection (ATR) method. The anisotropy of indices decreased for the film grown at the substrate temperature of 100° C. The optical anisotropy has been understood in terms of the molecular orientation.

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We have proposed a novel pretilt angle measurement method for twisted-nematic (TN) liquid-crystal (LC) cells. In this method, the dependence of the apparent retardation of the TN cell on the cell rotation angle is analyzed by the simple mathematic equations derived here to determine the pretilt angle and the gap. This method can be applied to the TN LC display panel. The necessary range of the cell rotation angle is from −3 • to 3 • . This provides an advantage for both constructing a compact measurement system and measuring a small-size pixel.

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Relaxation dynamics from a higher triplet excited state in R-sexithienyl (hereafter abbreviated as 6T) film was investigated by double-pulse excitation spectroscopy. Very rapid formation (within 1 ps) of the lowest singlet excited state and an intermolecular ion-pair state were observed. The mechanism of this rapid conversion process from a higher electronic excited state was discussed.

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