Sub-100 nm resolution on a 200 mm silicon stamp has been hot embossed into commercial Sumitomo NEB 22 resist. A single pattern, exposed with electron beam lithography, has been considered to define the stamp and thus make it possible to point out the impact of stamp design on the printing. These results may be considered as a first attempt to define rules to solve the proximity printing effects (PPEs). Moreover, a large range of initial resist thickness, from 56 to 506 nm, has been spin coated to assess the effect of polymer flow properties for the stamp cavity filling and the printed defects. A detailed analysis of the printed resist in dense hole patterns showed that the application volume conservation is enough to calculate the residual layer thickness as the height of the printed resist feature. Good accordance has been obtained between the theoretical approach and experimental results. Moreover, the impact of the pattern symmetry breakdown on mould deformation is clearly shown in this paper in the printed areas as well as in the unprinted areas.
This letter presents a study of viscous smoothening dynamics of a nanopatterned thin film. Ultrathin film manufacturing processes appearing to be a key point of nanotechnology engineering and numerous studies have been recently led in order to exhibit driving parameters of this transient surface motion, focusing on time scale accuracy method. Based on nanomechanical analysis, this letter shows that controlled shape measurements provided much more detailed information about reflow mechanism. Control of reflow process of any complex surface shape, or measurement of material parameter as thin film viscosity, free surface energy, or even Hamaker constant are therefore possible.
Polystyrene films, with thickness ranging from a few tens of nanometers up to several hundreds of nanometers and molecular weight of 27.5 kg mol−1, were patterned with nanoimprint lithography (NIL) technique. A rigid silicon stamp containing nanoscale features was printed into a thin spin coated polystyrene film. Then these patterns were annealed above the glass transition temperature in order to characterize the viscous reflow of the topography. Special attention was paid to provide, at initial times, imprinted nanoscale patterns with a very small aspect ratio and amplitude/wavelength as well as to avoid the nucleation of holes during imprinting or during the course of the reflow. This allowed the authors to process topography data with a high degree of accuracy from a linear viscous stability model. Atomic force microscopy measurements, with a spatial resolution lower than 1 nm, were used to characterize smooth or steep shapes. The mechanical measurements of earlier stages of pattern reflow were directly accessible without any assumption, contrary to the diffraction method usually employed. Our results clearly demonstrate that even the earliest stages of pattern reflow are driven by simple viscous effects and that relaxation dynamics, which is usually considered as following exponential laws, could be more complex. This article also demonstrates that the NIL process can be used for viscosity measurements for ultrathin resist film.
The nanoimprint lithography process consists of two mechanical steps: molding and stamp removal. While many publications dealing with anti-sticking layer properties or the understanding of polymer flow during imprinting have recently been published, only a few studies have been carried out to deeply characterize the demolding step. Regarding the small amount of theoretical work dedicated to this issue, in this paper both experimental and first theoretical approaches are proposed to characterize the demolding process in a peeling scheme. Full 200 mm stamp and imprinted wafers were used to identify the experimental limitation of such a full wafer peeling demolding scheme. A rectangular stamp and substrate samples with or without nanoscale features combined with an augmented beam theory are proposed to extract quantitative data for the required demolding force as well as the friction stress along the feature sidewall. Therefore both adhesion and friction forces were characterized on single stamp structures.
Annealing effects onto the reflow of imprinted resist patterns have been investigated on 250 nm dense line arrays printed with standard hot embossing lithography and thermoplastic polymer. Atomic force microscopy measurements were performed to point out the annealing temperature and time effects, respectively. The reflow velocity with respect to annealing temperature has been determined. Its variation is ascribed to both resist dynamic viscosity and surface free energy. Our approach demonstrated that imprint cycle time could be significantly reduced by saving cooling down time.
It is well known that one limitation of thermal nanoimprint lithography is the difficulty to imprint simultaneously nano-and microstructures because of the resulting different residual layer thicknesses, which induce a very poor control of the pattern sizes during the etching steps. Line gratings with densities varying from 1 to 15 have been imprinted on 8 in. wafers. The residual thickness varies from 38 to 158 nm. Different plasma chemistries have been studied for the etching of the residual layer. The patterns have been characterized after the imprint and the etching steps by scatterometry. The results show that some chemistries are very promising for the control of the patterns during the etching step. A O2/C12/Ar process has been particularly studied, and it has been demonstrated that it presents a very high anisotropy, which allows the use of long etching times in order to remove the residual layer in gratings with various densities with no variation of the critical dimension.
Nanoimprint lithography (NIL) processes are often plagued by different kinds of defects. The so-called capillary bridge is related to capillary forces between the stamp surface and the polymer during the pressing process. These defects affect both the printed and unprinted areas of the polymer film. Implementation of NIL as an industrial process requires that these defects be understood and minimized. As such, establishing a relationship between capillary bridge growing and pressing conditions, specifically the mold to polymer distance, is a key step. Two NIL stamps with various feature depths (12–224nm) were studied in this work to establish a link between bridge formation and mold filling. Printing processes were performed using small forces to guarantee contact between the mold and resist without totally filling stamp cavities. The resulting capillary bridges were characterized as a function of cavity depth and printing temperature. Results indicate that the number of defects is strongly influenced by the cavity size for depths <80nm as well as printing temperature.
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