A simple method is presented for synthesizing large single crystal graphene domains on melted copper using atmospheric pressure chemical vapor deposition (CVD). This is achieved by performing the reaction above the melting point of copper (1090 °C) and using a molybdenum or tungsten support to prevent balling of the copper from dewetting. By controlling the amount of hydrogen during growth, individual single crystal domains of monolayer graphene greater than 200 μm are produced within a continuous film. Stopping growth before a complete film is formed reveals individual hexagonal domains of graphene that are epitaxially aligned in their orientation. Angular resolved photoemission spectroscopy is used to show that the graphene grown on copper exhibits a linear dispersion relationship and no sign of doping. HRTEM and electron diffraction reveal a uniform high quality crystalline atomic structure of monolayer graphene.

The existence of a nematic phase transition in iron-chalcogenide superconductors poses an intriguing question about its impact on superconductivity. To understand the nature of this unique quantum phase transition, it is essential to study how the electronic structure changes across this transition at low temperatures. Here, we investigate the evolution of the Fermi surfaces and electronic interactions across the nematic phase transition of FeSe 1−x S x using Shubnikov-de Haas oscillations in high magnetic fields up to 45 T in the low temperature regime down to 0.4 K. Most of the Fermi surfaces of FeSe 1−x S x monotonically increase in size except for a prominent low frequency oscillation associated with a small, but highly mobile band, which disappears at the nematic phase boundary near x~0.17, indicative of a topological Lifshitz transition. The quasiparticle masses are larger inside the nematic phase, indicative of a strongly correlated state, but they become suppressed outside it. The experimentally observed changes in the Fermi surface topology, together with the varying degree of electronic correlations, will change the balance of electronic interactions in the multi-band system FeSe 1−x S x and promote different k z-dependent superconducting pairing channels inside and outside the nematic phase.

Progress in superconducting bulk materials has been somewhat overshadowed by the considerable effort required to produce practical long-length conductors. There has, however, been steady progress in both the materials science of bulk superconducting materials and the technologies required to use them effectively in engineering applications. In particular, magnetised bulk superconductors are capable of acting as quasi-permanent magnets with the potential of providing magnetic fields of several tesla or greater from a small volume of material, they can act as magnetic shields and they can provide self-stabilised levitation. This roadmap, based on a workshop which involved the participation of a wide range of academic and industrial participants (see doi: 10.17863/CAM.586 for details of the workshop methodology), aims to explore some of the key potential domains of application of bulk superconductors. Detailed technological roadmaps are presented for four key applications that were identified as providing both good market opportunity and feasibility. These are: portable systems for bulk superconductivity; portable, high-field magnet systems for medical devices; ultra-light superconducting rotating machines for next-generation transport & power applications; and magnetic shielding applications for electric machines, equipment and other high-field devices.

3D printing is used extensively in product prototyping and continues to emerge as a viable option for the direct manufacture of final parts. It is known that dielectric materials with relatively high real permittivity—which are required in important technology sectors such as electronics and communications—may be 3D printed using a variety of techniques. Among these, the fused deposition of polymer composites is particularly straightforward but the range of dielectric permittivities available through commercial feedstock materials is limited. Here we report on the fabrication of a series of composites composed of various loadings of BaTiO3 microparticles in the polymer acrylonitrile butadiene styrene (ABS), which may be used with a commercial desktop 3D printer to produce printed parts containing user-defined regions with high permittivity. The microwave dielectric properties of printed parts with BaTiO3 loadings up to 70 wt% were characterised using a 15 GHz split post dielectric resonator and had real relative permittivities in the range 2.6–8.7 and loss tangents in the range 0.005–0.027. Permittivities were reproducible over the entire process, and matched those of bulk unprinted materials, to within ~1%, suggesting that the technique may be employed as a viable manufacturing process for dielectric composites.

Persistent current joints are crucial components of superconducting magnets—enabling the production of the high and ultra-stable magnetic fields required, for instance, for magnetic resonance measurements. At this critical juncture when persistent mode magnets containing commercial high temperature superconductors may soon become a reality, it is of value to take stock and evaluate current challenges faced in the field of jointing. This paper provides a review of progress made to date on the production and characterization of joints between the five major technological superconductors—NbTi, Nb3Sn, MgB2, BiSCCO and REBCO, including the materials that are used to make these joints.

Breaking the time reversal symmetry of a topological insulator, for example by the presence of magnetic ions, is a prerequisite for spinbased electronic applications in the future. In this regard Mn-doped Bi 2 Te 3 is a prototypical example that merits a systematic investigation of its magnetic properties. Unfortunately, Mn doping is challenging in many host materials-resulting in structural or chemical inhomogeneities affecting the magnetic properties. Here, we present a systematic study of the structural, magnetic and magnetotransport properties of Mn-doped Bi 2 Te 3 single crystals using complimentary experimental techniques. These materials exhibit a 6 Authors contributed equally to this work. 7

Monolayer graphene with large domain sizes can be grown by chemical vapor deposition using a Cu catalyst in its molten state. However, extending this to fully continuous sheets of graphene on the centimeter scale is challenging, because of cracks, rips, and tears that are induced upon rapid cooling. The various issues that prohibit fully continuous graphene sheets are identified and solutions presented. These include (i) developing a novel two-stage CVD growth process that fills in the cracks and holes formed upon cooling; (ii) appropriate choice of underlying wetting substrate of W, instead of Mo, which causes holes; and (iii) a new electrochemical transfer method that removes W and then Cu to enable the efficient transfer of crack-free graphene sheets onto silicon wafers. Our results provide important solutions to challenges related to the synthesis and transfer of high-quality monolayer graphene grown on molten Cu catalysts for electronic applications.

Abstract. The interplay between superconductivity, magnetism and crystal structure in iron-based superconductors is a topic of great interest amongst the condensed matter physics community as it is thought to be the key to understanding the mechanisms responsible for high temperature superconductivity. Alkali metal doped iron chalcogenide superconductors exhibit several unique characteristics which are not found in other iron-based superconducting materials such as antiferromagnetic ordering at room temperature, the presence of ordered iron vacancies and high resistivity normal state properties. Detailed microstructural analysis is essential in order to understand the origin of these unusual properties. Here we have used a range of complementary scanning electron microscope based techniques, including high-resolution electron backscatter diffraction mapping, to assess local variations in composition and lattice parameter with high precision and sub-micron spatial resolution. Phase separation is observed in the Cs x Fe 2−y Se 2 crystals, with the minor phase distributed in a plate-like morphology throughout the crystal. Our results are consistent with superconductivity occurring only in the minority phase.