Easy access on water: A cobalt‐catalyzed asymmetric preparation of trifluoromethylcyclopropanes has been developed that yields high enantioselectivities with a broad range of styrene substrates (see scheme). The reaction presents a new access to enantioenriched CF3‐containing building blocks.

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Double patterning lithography has been one of the candidates for sub-40nm patterning era, and has a lot of process issues to be confirmed. Last year, we presented the issues in double patterning lithography with a real flash gate pattern. Process flow was suggested and CD uniformity due to overlay was analyzed. And the layout decomposition and the two types of double patterning of positive and negative tone were studied with 1-dimensional pattern. In this paper, the implementation to DRAM patterns is examined, which consist of 2-dimensional patterns. Double patterning methods and the selection of their tone for each layer are studied, and the difficulties from the randomness of core pattern are also considered. As a result, DRAM patterns have more restrictions on the double patterning method and selection of tone, and the aggressive layout decomposition should be designed to solve the difficulty in core patterning. Therefore, 37nm DRAM layout can be patterned and the overlay control and cost still remain as dominant obstacles.

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In the field of lithography technology, EUV lithography can be a leading candidate for sub-30 nm technology node. EUVL expose system has different characteristics compared to DUV exposure system. EUV source wavelength is short and no material is transparent to the source. So off-axis reflective optic system is used for patterning in place of on-axis refractive system of DUV system. And different reticle design is needed that consists of 40 pair of Mo/Si multi layer and absorber layer in place of conventional mask. Because of the oblique incidence on the mask, shadowing effect is occurred such as pattern asymmetry, shift and pattern bias depending on pattern orientation. For non-telecentric characteristics of EUV scanner, shadowing effect produces CD variation versus field position[1] [2]. Besides, it is well known that EUV scanner has bigger flare than conventional DUV scanner. Therefore, the correction of mask shadowing effect and flare level are one of the important issues for EUV lithography.In this paper, process window and MEF of EUV lithography has been examined by 3D mask simulation. CD variation by shadowing is simulated for various pattern orientations. A shadowing correction method has been calculated due to field position to reduce shadowing effect. And the correction effect is examined by simulation and Experimental results. Principle of radial overlay shift due to field position is verified then the shift length of line and space pattern is calculated.