In organic photovoltaic (OPV) cells, photocurrent generation relies on exciton diffusion to the donor/acceptor heterojunction. Excitons that fail to reach the heterojunction are lost to recombination via quenching at the electrodes or relaxation in the bulk. Bulk recombination has been mitigated largely through the use of bulk heterojunctions, while quenching at the metal cathode has been previously circumvented through the introduction of exciton blocking layers that “reflect” excitons. Here, we investigate an alternative concept of a transparent exciton dissociation layer (EDL), a single layer that prevents exciton quenching at the electrode while also providing an additional interface for exciton dissociation. The additional heterojunction reduces the distance excitons must travel to dissociate, recovering the electricity-generating potential of excitons otherwise lost to heat. We model and experimentally demonstrate this concept in an archetypal subphthalocyanine/fullerene planar heterojunction OPV, generating an extra 66% of photocurrent in the donor layer (resulting in a 27% increase in short-circuit current density from 3.94 to 4.90 mA/cm2). Because the EDL relaxes the trade-off between exciton diffusion and optical absorption efficiencies in the active layers, it has broad implications for the design of OPV architectures and offers additional benefits over the previously demonstrated exciton blocking layer for photocurrent generation.

a b s t r a c tTo probe the influence of molecular dipole on the open circuit voltage (V OC ) of molecular heterojunction organic solar cells, we study axially fluorinated boron subphthalocyanine/ fullerene (SubPc-F/C 60 ) junctions. These exhibit an open-circuit voltage V OC = 1.00 V, a value closer to the HOMO-LUMO offset at the donor-acceptor interface = 1.69 eV than the V OC = 1.06 V measured for junctions between the archetypal chlorinated SubPc and C 60 , with corresponding HOMO-LUMO offset = 1.84 eV. Aside from the axial halogen substitution, the two compounds exhibit similar molecular structure and optical absorption. The energy levels and structure of the heteromolecular polaron pair are calculated, and the ideal organic diode model for SubPc-Cl is modified accordingly, successfully reproducing the experimental SubPc-F device characteristics. The reproducible difference in V OC is attributed to the different electric dipole strength between SubPc-F and SubPc-Cl and its influence on polaron pair dynamics at the heterojunction.

Technetium-99 PyP scanning is a useful adjunct in predicting the need for amputation in extremities damaged by electrical injury, frostbite, or invasive infection. In addition, by providing an objective "picture" of extremity perfusion, PyP scans can be helpful in convincing patients of the need for amputation.

Fast deposition of thin films is essential for achieving low-cost, high-throughput phosphorescent organic light-emitting diode (PHOLED) production. In this work, we demonstrate rapid and uniform growth of semiconductor thin films by organic vapor phase deposition (OVPD). A green PHOLED comprising an emission layer (EML) grown at 50 Å/s with bis­[2-(2-pyridinyl-N)­phenyl-C]­(acetyl­acetonato)­iridium­(III) (Ir­(ppy)2(acac)) doped into 4,4′-bis­(N-carbazolyl)-1,1′-biphenyl (CBP) exhibits a maximum external quantum efficiency of 20 ± 1%. The morphology, charge transport properties, and radiative efficiency under optical and electrical excitation of the PHOLED EML are investigated as functions of the deposition rate via both experimental and theoretical approaches. The EML shows no evidence for gas phase nucleation of the organic molecules at deposition rates as high as 50 Å/s. However, the roll-off in quantum efficiency at high current progressively increases with deposition rate due to enhanced triplet-polaron annihilation. The roll-off results from accumulation of stress within the PHOLED EML that generates a high density of defect states. The defects, in turn, act as recombination sites for triplets and hole polarons, leading to enhanced triplet-polaron annihilation at high current. We introduce a void nucleation model to describe the film morphology evolution that is observed using electron microscopy.

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This study focuses on the fabrication and performance testing of unsupported platinum black electrodes for proton exchange membrane fuel cells. Experiments with platinum black coated diffusion media of varying anode and cathode catalyst loadings with H 2 /air demonstrate successful performance and stability characteristics for anode catalyst loadings down to 0.25 mg/cm 2 while operating on pure H 2 and 0.62 mg/cm 2 cathode catalyst loadings, without significant voltage losses. The voltage losses as a result of reducing the platinum black cathode catalyst loadings from 2.6 to 0.62 mg/cm 2 are consistent with kinetic losses associated with the oxygen reduction reaction and lower electrocatalyst utilization. The study also highlights the durability and stability characteristics of these unsupported electrodes under extreme operating conditions. Optimization of the three-phase interface, namely electrode, electrolyte, and reactant gas, is shown to be dependent on the efficacy of the membrane-catalyst layer interface.

Up to now, the analysis of organic or biological samples was mainly investigated using static SIMS, while dynamic SIMS was generally limited to the analysis of inorganic samples. The increasing sophistication of organic optoelectronic devices (e.g. organic light emitting diodes and organic photovoltaic cells, etc.) requires molecular-level dimensional control in the fabrication of multilayered structures with specifically engineered interfaces. However, analytical tools for monitoring such fabrication precision are scarce. In a current project, we address this challenge by advancing the development of low-energy Secondary Ion Mass Spectrometry (LE-SIMS) for the analysis of organic-based optoelectronic materials systems.In the present work, we investigate the fragmentation as well as the ionization mechanisms for several molecules used in such devices: fullerene, copper phthalocyanine and tris(8-hydroxyquinolinato) aluminium have been deposited onto silicon wafers. The study has been carried out on a Cameca SC-Ultra instrument under Cs + bombardment for various impact energies in the M − mode. Constant M − secondary ion intensities have been observed throughout the organic layers for some characteristic fragments of the organic molecules.

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