Sustainably produced biofuels, especially when they are derived from lignocellulosic biomass, are being discussed intensively for future ground transportation. Traditionally, research activities focus on the synthesis process, while leaving their combustion properties to be evaluated by a different community. This Review adopts an integrative view of engine combustion and fuel synthesis, focusing on chemical aspects as the common denominator. It will be demonstrated that a fundamental understanding of the combustion process can be instrumental to derive design criteria for the molecular structure of fuel candidates, which can then be targets for the analysis of synthetic pathways and the development of catalytic production routes. With such an integrative approach to fuel design, it will be possible to improve systematically the entire system, spanning biomass feedstock, conversion process, fuel, engine, and pollutants with a view to improve the carbon footprint, increase efficiency, and reduce emissions.

A well-to-wheel LCA shows that OME1could serve as an almost carbon-neutral blending component in diesel while even also strongly reducing the NOx and soot emissions.

Within the Cluster of Excellence "Tailor-Made Fuels from Biomass", a new reaction sequence to transform biomass into 2-methylfuran has been developed. In the present study, the influence of this potential biofuel on in-cylinder spray formation and evaporation as well as engine performance is studied experimentally using a direct-injection spark-ignition single-cylinder research engine. The results obtained for 2-methylfuran are benchmarked against investigation on the same engine using conventional research octane number (RON) 95 fuel and ethanol. The in-cylinder spray formation and evaporation process is characterized by high-speed Mie scattering visualizations, indicating quicker evaporation of 2-methylfuran compared to ethanol. Engine experiments support the findings of the optical measurements by revealing excellent combustion stability, especially in cold conditions, combined with a hydrocarbon emission reduction of at least 61 % in the relevant spark timing range compared to conventional fuel. The enleanment capability was also found to be higher by 0.16 units of relative air/fuel ratio. A noticeable drawback resulting from the combustion of 2-methylfuran is higher emissions of nitrogen oxides. The knock resistance of 2-methylfuran at full load is significantly better compared to RON 95, however, worse than ethanol. It allows for a compression ratio increase of more than 3.5 units compared to RON 95. The measured efficiency benefits with a compression ratio increase of 3.5 units range up to 9.9 % at full load.

Increasing carbon dioxide accumulation in earth's atmosphere and the depletion of fossil resources pose huge challenges for our society and, in particular, for all stakeholders in the transportation sector. The Cluster of Excellence 'Tailor-Made Fuels from Biomass' at RWTH Aachen University establishes innovative and sustainable processes for the conversion of whole plants into molecularly well-defined fuels exhibiting tailored properties for low-temperature combustion engine processes, enabling high efficiency and low pollutant emissions. The concept of fuel design, that is, considering fuel's molecular structure to be a design degree of freedom, aims for the simultaneous optimisation of fuel production and combustion systems. In the present contribution, three examples of tailor-made biofuels are presented. For spark ignition engines, both 2-methylfuran and 2-butanone show increased knock resistance compared to RON95 gasoline, thus enabling a higher compression ratio and an efficiency gain of up to 20% at full-load operation. Moreover, both fuels comprise a good mixture formation superior to the one of ethanol, especially under difficult boundary conditions. For compression ignition engines, 1-octanol enables a remarkable reduction in engine-out soot emissions compared to standard diesel fuel due to the high oxygen content and lower reactivity. This advantage is achieved without sacrificing the high indicated efficiency and low NO X emissions.

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