Optical ignition of solid energetic materials, which can rapidly release heat, gas, and thrust, is still challenging due to the limited light absorption and high ignition energy of typical energetic materials (e.g., aluminum, Al). Here, we demonstrated that the optical ignition and combustion properties of micron-sized Al particles were greatly enhanced by adding only 20 wt % of graphene oxide (GO). These enhancements are attributed to the optically activated disproportionation and oxidation reactions of GO, which release heat to initiate the oxidization of Al by air and generate gaseous products to reduce the agglomeration of the composites and promote the pressure rise during combustion. More importantly, compared to conventional additives such as metal oxides nanoparticles (e.g., WO 3 and Bi 2 O 3 ), GO has much lower density and therefore could improve energetic properties without sacrificing Al content. The results from Xe flash ignition and laser-based excitation experiments demonstrate that GO is an efficient additive to improve the energetic performance of micron-sized Al particles, enabling micron-sized Al to be ignited by optical activation and promoting the combustion of Al in air.
Thermite, a composite
of metal and metal oxide, finds wide applications
in power and thermal generation systems that require high-energy density.
Most of the researches on thermites have focused on using aluminum
(Al)
particles as the fuel. However, Al particles are sensitive to electrostatic
discharge, friction, and mechanical impact, imposing a challenge for
the safe handling and storage of Al-based thermites. Silicon (Si)
is another attractive fuel for thermites because of its high-energy
content, thin native oxide layer, and facile surface functionality.
Several studies showed that the combustion properties of Si-based
thermites are comparable to those of Al-based thermites. However,
little is known about the ignition properties of Si-based thermites.
In this work, we determined the reaction onset temperatures of mechanically
mixed (MM) Si/Fe
2
O
3
nanothermites and Si/Fe
2
O
3
core/shell (CS) nanothermites using differential
scanning calorimetry. The Si/Fe
2
O
3
CS nanothermites
were prepared by an electroless deposition method. We found that the
Si/Fe
2
O
3
CS nanoparticles (NPs) had a lower
reaction onset temperature (∼550 °C) than the MM Si/Fe
2
O
3
nanothermites (>650 °C). The onset temperature
of the Si/Fe
2
O
3
CS nanothermites is also insensitive
to the size of the Si core NP. These results indicate that the interfacial
contact quality between Si and Fe
2
O
3
is the
dominant factor for determining the ignition properties of thermites.
Finally, the reaction onset temperature of the Si/Fe
2
O
3
CS NPs is comparable to that of the commonly used Al-based
nanothermites, suggesting that Si is an attractive fuel for thermites.
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