To evaluate the binding equilibrium in the nuclease reactions of Cu(Phen)~ the interaction of few copper complexes having positive redox potentials relative to the artificial nuc]ease Cu(Phen)~ with calf thymus DNA have been investigated using spectroscopic and voltammetric studies. Electronic and EPR spectral and electrochemical studies have been carried out for the interaction of cu(dpsmp)z z-/a-[dpsmp =
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