No abstract

Ammonia synthesis at 533 K and atmospheric pressure was investigated in a coaxial dielectric barrier discharge (DBD) plasma reactor without packing and with porous γ-Al2O3, 5 wt % Ru/γ-Al2O3, or 5 wt % Co/γ-Al2O3 catalyst particles. Gas-phase species were monitored in situ using an electron impact molecular-beam mass spectrometer (EI-MBMS). Gas-phase species NNH and N2H2 were first identified under common conditions of plasma-assisted ammonia synthesis and were present at levels comparable to that of NH3 in the plasma discharge. Concentrations of NNH, N2H2, and NH in a reactor packed with γ-Al2O3 or other particles were lower than those observed in an empty reactor, while the concentration of NH3 increased. These observations point to the importance of NNH and N2H2 in plasma-assisted surface reactions in ammonia synthesis. Reaction pathways of direct adsorption of gas-phase NNH and N2H2 on solid surfaces and subsequent reactions were proposed. This study demonstrated that in situ identification of gas-phase species via EI-MBMS provides a powerful approach to study the kinetics of plasma-assisted catalysis.

No abstract

N-(4-alkoxyphenyl) substituted poly(carbazol-2,7-ylene)s were synthesized by Ni-catalyzed polycondensations of 2,7-dihalogenocarbazoles. The polymers intensely fluoresced blue in solution and in the solid-film state by irradiation of UV light. The introduction of the aryl group at the N-position of poly(carbazol-2,7-ylene) enhanced fluorescent quantum efficiency of the polymer, which showed higher performance than N-alkyl substituted polymers.

No abstract

The present status of kinetic modeling of particle dynamics in hydrogen negative ion (H − ) source plasmas and their comparisons with experiments are reviewed and discussed with some new results. The main focus is placed on the following topics, which are important for the research and development of H − sources for intense and high-quality H − ion beams: (i) effects of non-equilibrium features of electron energy distribution function on volume and surface H − production, (ii) the origin of the spatial non-uniformity in giant multi-cusp arc-discharge H − sources, (iii) capacitive to inductive (E to H) mode transition in radio frequency-inductively coupled plasma H − sources and (iv) extraction physics of H − ions and beam optics, especially the present understanding of the meniscus formation in strongly electronegative plasmas (so-called ion-ion plasmas) and its effect on beam optics. For these topics, mainly Japanese modeling activities, and their domestic and international collaborations with experimental studies, are introduced with some examples showing how models have been improved and to what extent the modeling studies can presently contribute to improving the source performance. Close collaboration between experimental and modeling activities is indispensable for the validation/improvement of the modeling and its contribution to the source design/development. chamber wall (anode) and filaments (cathode). In the latter sources, the RF-electromagnetic field is used to generate and heat plasmas.In this review, we mainly focus on the modeling studies, especially the modeling study of H − source plasmas using kinetic approaches, such as the test particle Monte-Carlo model [14] and particle in cell (PIC) model [14,15], which has been reviewed in [16]. Here, we extend it with some new results. Close collaboration between the experimental and modeling study is very important as it can improve our basic understanding of source plasmas. Various examples of the model validation will be shown through comparisons with experiments and also how modeling studies contribute to the improvement of source performances.As for the multi-cusp arc-discharge source, we will first show a systematic study to help us understand the role of the EEDF on the H − VP in section 2.2. The study has been carried out for a compact multi-cusp arcdischarge source (SHI H − source: Sumitomo Heavy Industry H − source [17,18]) for medical application such as boron neutron capture therapy and the radioisotope production for molecular imaging technology.The SHI H − source is a typical tandem type H − source [19]. In such a tandem type volume sources, the plasma source volume is divided into two regions by the transverse magnetic field (the so-called magnetic filter filed: MF-field) to control the EEDFs and to promote the two step H − VP reactions explained above. Namely, the source volume consists of two regions: (1) the 'driver region' where the electron energy is high and the EV process is promoted, and (2) the 'extraction region' where the electr...

No abstract

DIII-D physics research addresses critical challenges for the operation of ITER and the next generation of fusion energy devices. This is done through a focus on innovations to provide solutions for high performance long pulse operation, coupled with fundamental plasma physics understanding and model validation, to drive scenario development by integrating high performance core and boundary plasmas. Substantial increases in off-axis current drive efficiency from an innovative top launch system for EC power, and in pressure broadening for Alfven eigenmode control from a co-/counter-I p steerable off-axis neutral beam, all improve the prospects for optimization of future long pulse/steady state high performance tokamak operation. Fundamental studies into the modes that drive the evolution of the pedestal pressure profile and electron vs ion heat flux validate predictive models of pedestal recovery after ELMs. Understanding the physics mechanisms of ELM control and density pumpout by 3D magnetic perturbation fields leads to confident predictions for ITER and future devices. Validated modeling of high-Z shattered pellet injection for disruption mitigation, runaway electron dissipation, and techniques for disruption prediction and avoidance including machine learning, give confidence in handling disruptivity for future devices. For the non-nuclear phase of ITER, two actuators are identified to lower the L–H threshold power in hydrogen plasmas. With this physics understanding and suite of capabilities, a high poloidal beta optimized-core scenario with an internal transport barrier that projects nearly to Q = 10 in ITER at ∼8 MA was coupled to a detached divertor, and a near super H-mode optimized-pedestal scenario with co-I p beam injection was coupled to a radiative divertor. The hybrid core scenario was achieved directly, without the need for anomalous current diffusion, using off-axis current drive actuators. Also, a controller to assess proximity to stability limits and regulate β N in the ITER baseline scenario, based on plasma response to probing 3D fields, was demonstrated. Finally, innovative tokamak operation using a negative triangularity shape showed many attractive features for future pilot plant operation.