The rheological properties of aqueous suspensions based on three different nanocelluloses were compared. One system was obtained via acid hydrolysis (thus yielding crystalline nanocellulose, CNC) and the other two from mechanical shearing, but from different origins and subjected to different pretreatments. Of the latter two, one was considered to be a rather typical cellulose nanofibril (CNF) suspension whereas the other was a kind of intermediate between CNF and CNC. All three nanocellulose elements differed in dimensions as evident from transmission electron microscopy and atomic force microscopy. With regard to the length of the fibrils/particles, the three nanocelluloses formed three distinct groups with lengths between 200 and slightly more than 800 nm. The three cellulosic elements were also subjected to a TEMPO-mediated oxidation yielding a similar carboxylate content in the three systems. Furthermore, the TEMPO-oxidized elements were grafted with poly(ethylene glycol) (PEG). The amount of grafted PEG was about 35 wt%. The shear viscosity, the storage modulus and the loss modulus of suspensions of the unmodified, the TEMPO-oxidized and the grafted nanocelluloses were determined at room temperature and the solids content of the suspensions was varied between 0.7 and 2.0 wt%. It was concluded that the rheological properties varied significantly between the suspensions depending on the dimensions of the cellulosic elements and their surface characteristics. In this context, the length (or the aspect ratio) of the particles played a very important role.
In
current times, CO2 capture and lightweight energy
storage are receiving significant attention and will be vital functions
in next-generation materials. Porous carbonaceous materials have great
potential in these areas, whereas most of the developed carbon materials
still have significant limitations, such as nonrenewable resources,
complex and costly processing, or the absence of tailorable structure.
In this study, a new strategy is developed for using the currently
underutilized lignin and cellulose nanofibers, which can be extracted
from renewable resources to produce high-performance multifunctional
carbon aerogels with a tailorable, anisotropic pore structure. Both
the macro- and microstructure of the carbon aerogels can be simultaneously
controlled by carefully tuning the weight ratio of lignin to cellulose
nanofibers in the precursors, which considerably influences their
final porosity and surface area. The designed carbon aerogels demonstrate
excellent performance in both CO2 capture and capacitive
energy storage, and the best results exhibit a CO2 adsorption
capacity of 5.23 mmol g–1 at 273 K and 100 kPa and
a specific electrical double-layer capacitance of 124 F g–1 at a current density of 0.2 A g–1, indicating
that they have great future potential in the relevant applications.
Various carbon materials have been developed for energy storage applications to address the increasing energy demand in the world. However, the environmentally friendly, renewable, and nontoxic bio-based carbon resources have not been extensively investigated towards high-performance energy storage materials. Here, we report an anisotropic, hetero-porous, high-surface area carbon aerogel prepared from renewable resources achieving an excellent electrical double-layer capacitance. Two different green, abundant, and carbon-rich lignins which can be extracted from various biomasses, have been selected as raw materials, i.e., kraft and soda lignins, resulting in clearly distinct physical, structural as well as electrochemical characteristics of the carbon aerogels after carbonization. The obtained green carbon aerogel based on kraft lignin not only demonstrates a competitive specific capacitance as high as 163 F g−1 and energy density of 5.67 Wh kg−1 at a power density of 50 W kg−1 when assembled as a two-electrode symmetric supercapacitor, but also shows outstanding compressive mechanical properties. This reveals the great potential of the carbon aerogels developed in this study for the next-generation energy storage applications requiring green and renewable resources, lightweight, robust storage ability, and reliable mechanical integrity.
Energy storage devices such as supercapacitors of high performance are in great need due to the continuous expansion of digitalization and related devices for mobile electronics, autonomous sensors, and vehicles of different kinds. However, the nonrenewable resources and often complex preparation processes associated with electrode materials and structures pose limited scale-up in production and difficulties in versatile utilization of the devices. Here, free-standing and flexible carbon nanofiber networks derived from renewable and abundant bioresources are demonstrated. By a simple optimization of carbonization, the carbon nanofiber networks reach a large surface area of 1670 m 2 g −1 and excellent specific gravimetric capacitance of ∼240 F g −1 , outperforming many other nanostructured carbon, activated carbon, and even those decorated with metal oxides. The remarkable electrochemical performance and flexibility of the green carbon networks enable an all-solid-state supercapacitor device, which displays a device capacitance of 60.4 F g −1 with a corresponding gravimetric energy density of 8.4 Wh kg −1 while maintaining good mechanical properties.
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