The aggregation-induced emission (AIE) phenomenon is important in organic light-emitting diodes (OLEDs), for it can potentially solve the aggregationcaused quenching problem. However, the performance of AIE fl uorophorbased OLEDs (AIE OLEDs) is unsatisfactory, particularly for deep-blue devices (CIEy < 0.15). Here, by enhancing the device engineering, a deep-blue AIE OLED exhibits low voltage (i.e., 2.75 V at 1 cd m −2 ), high luminance (17 721 cd m −2 ), high effi ciency (4.3 lm W −1 ), and low effi ciency roll-off (3.6 lm W −1 at 1000 cd m −2 ), which is the best deep-blue AIE OLED. Then, blue AIE fl uorophors, for the fi rst time, have been demonstrated to achieve high-performance hybrid white OLEDs (WOLEDs). The two-color WOLEDs exhibit i) stable colors and the highest effi ciency among pure-white hybrid WOLEDs (32.0 lm W −1 ); ii) stable colors, high effi ciency, and very low effi ciency roll-off; or iii) unprecedented effi ciencies at high luminances (i.e., 70.2 cd A −1 , 43.4 lm W −1 at 10 000 cd m −2 ). Moreover, a three-color WOLED exhibits wide correlated color temperatures (10 690-2328 K), which is the fi rst hybrid WOLED showing sunlight-style emission. These fi ndings will open a novel concept that blue AIE fl uorophors are promising candidates to develop high-performance hybrid WOLEDs, which have a bright prospect for the future displays and lightings.
In this work, an innovative all-sputtered bottom-gate thin film transistor (TFT) using an amorphous InGaZnO (IGZO)/Al2O3 bi-layer channel was fabricated by fully room temperature processes on a flexible PEN substrate.
Doping-free white organic light-emitting diodes (DF-WOLEDs) have aroused research interest because of their simple properties. However, to achieve doping-free hybrid WOLEDs (DFH-WOLEDs), avoiding aggregation-caused quenching is challenging. Herein, blue luminogens with aggregation-induced emission (AIE) characteristics, for the first time, have been demonstrated to develop DFH-WOLEDs. Unlike previous DFH-WOLEDs, both thin (<1 nm) and thick (>10 nm) AIE luminogen (AIEgen) can be used for devices, enhancing the flexibility. Two-color devices show (i) pure-white emission, (ii) high CRI (85), and (iii) high efficiency. Particularly, 19.0 lm W is the highest for pure-white DF-WOLEDs, while 35.0 lm W is the best for two-color hybrid WOLEDs with CRI ≥ 80. A three-color DFH-WOLED shows broad color-correlated temperature span (2301-11628 K), (i) the first sunlight-like OLED (2500-8000 K) operating at low voltages, (ii) the broadest span among sunlight-like OLED, and (iii) possesses comparable efficiency with the best doping counterpart. Another three-color DFH-WOLED exhibits CRI > 90 at ≥3000 cd m, (i) the first DF-WOLED with CRI ≥ 90 at high luminances, and (ii) the CRI (92.8) is not only the highest among AIE-based WOLEDs but also the highest among DF-WOLEDs. Such findings may unlock an alternative concept to develop DFH-WOLEDs.
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