Layers of ethylene carbonate (EC) modified CuI/PVA polymer composites were prepared by growth of CuI nano-particles in an aqueous solution of PVA followed by casting at room temperature. The structural, thermal, optical, electrical and di-electrical characterization of polymer composites was investigated using different techniques. These investigations confirm the growth of CuI nano-particles and reduction of PVA crystallinity by increasing ethylene carbonate concentration. These results show that energy band gap and bulk conductivity increase while activation energy reduces with the increase of EC concentration in the composite. Moreover, the variation of the dielectric permittivity and dielectric loss with EC content are found to obey Debye dispersion relations.
a b s t r a c tAn important issue in construction of organic photovoltaic cells concerns the selective contacts. Here, especially the modification of the hole-extraction is challenging, as energy levels have to match the polymer's highest occupied molecular orbital (HOMO). We took the view to the mutual anode interface and we sought for a solution-based alternative for commonly used PEDOT:PSS -with an eye on improving the hole-extraction with an inorganic interlayer. We present copper iodide (CuI) as a versatile inorganic p-type semiconductor that meets the requirements for enhanced charge extraction in donor polymers. We applied two types of anthracene-containing PPE-PPV block-copolymers that recently gained attention as efficient active absorbers in bulk heterojunction photovoltaic cells. We report on the advantages using CuI as hole-selective contact and show an improvement of the power conversion efficiency in polymer-based solar cells.
Lead sulfide quantum dots represent an emerging photovoltaic absorber material. While their associated optical qualities are true for the colloidal solution phase, they change upon processing into thin-films. A detailed view to the optical key-parameters during solid-film development is presented and the limits and outlooks for this versatile and promising absorber are discussed.
Aims: Typhoid is a serious disease difficult to be treated with conventional drugs. The aim of this study was to demonstrate a new method for the control of Salmonella typhi growth, through the interference with the bioelectric signals generated from the microbe during cell division by extremely low frequency electromagnetic waves (ELF-EMW-ELF-EM) at resonance frequency. Methods and Results: Isolated Salmonella typhi was subjected to square amplitude modulated waves (QAMW) with different modulation frequencies from two generators with constant carrier frequency of 10 MHz, amplitude of 10 Vpp, modulating depth AE 2 Vpp and constant field strength of 200 V m À1 at 37°C. Both the control and exposed samples were incubated at the same conditions during the experiment. The results showed that there was highly significant inhibition effect for Salm. typhi exposed to 0Á8 Hz QAMW for a single exposure for 75 min. Dielectric relaxation, TEM and DNA results indicated highly significant changes in the molecular structure of the DNA and cellular membrane resulting from the exposure to the inhibiting EM waves. Conclusions: It was concluded that finding out the inhibiting resonance frequency of ELF-EM waves that deteriorates Salm. typhi growth will be promising method for the treatment of Salm. typhi infection either in vivo or in vitro. Significance and Impact of the Study: This new non-invasive technique for treatment of bacterial infections is of considerable interest for the use in medical and biotechnological applications.
This paper develops a simple, cost-effective, fully Inkjet-printed flexible temperature sensor with easy fabrication steps using PiXDRO LP50 inkjet printer. The thermistor sensor employed a Poly(3,4ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT: PSS) as a temperature-sensitive layer with silver nanoparticles (AgNps) as a contact electrode. The sensor performance was evaluated on different dimensions and types of substrates. Epson Glossy paper with 255 µm thickness and Polyimide (Kapton HN) with 50 µm thickness were used over temperatures ranging from room temperature up to 50 ⁰C and 90 ⁰C for paper and Kapton substrates, respectively. The sensor developed over Glossy paper showed the best sensitivity of -1.67 %/⁰C in the chosen temperature range while the sensor showed +0.113%/⁰C on PI substrate.
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