A single PEMFC has been operated by varying the assembly temperature, the air dew point temperature and the anode/cathode stoichiometry rates with the aim to identify the parameters and combinations of factors affecting the cell performance. Some of the experiments were conducted with low humidified reactants (relative humidity of 12%). The FC characterizations tests have been conducted using in-situ electrochemical methods based on load current and cell voltage signal analysis, namely: polarization curves, EIS measurements, cyclic and linear sweep voltammetries (CV and LSV). The impacts of the parameters on the global FC performances were observed using the polarization curves whereas EIS, CV and LSV test results were used to discriminate the different voltage loss sources. The test results suggest that some parameter sets allow maximal output voltages but can also induce material degradation. For instance, higher FC temperature and air flow values can induce significant electrical efficiency benefits, notably by increasing the reversible potential and the reaction kinetics. However, raising the cell temperature can also gradually dry the FC and increase the risk of membrane 2 failure. LSV has also shown that elevated FC temperature and relative humidity can also accelerate the electrolyte degradation (i.e. slightly higher fuel crossover rate) and reduce the lifetime consequently.
The increasing interest in Hybrid Electric Vehicles led to the study of new powertrain structures. In particular, it was demonstrated in the technical literature how series architecture can be more efficient, compared to parallel one, if supercapacitors are used as storage system. Since supercapacitors are characterized by high efficiency and high power density, but have low specific energy, storage sizing is a critical point with this technology. In this study, a detailed analysis on the effect of supercapacitor storage sizing on series architecture was carried out. In particular, in series architecture, supercapacitor storage sizing influences both engine number of starts and the energy that can be stored during regenerative braking. The first aspect affects the comfort, whereas the second aspect directly influences powertrain efficiency. Vehicle model and Energy Management System were studied and simulations were carried out for different storage energy, in order to define the optimal sizing.
In the area of fuel cell research, most of the experimental techniques and equipments are still devoted to the analysis of single cells or very short stacks. However, the diagnosis of fuel cell stacks providing significant power levels is a critical aspect to be considered for the integration of fuel cell systems into real applications such as vehicles or stationary gensets. In this article, a new instrument developed in-lab is proposed in order to satisfy the requirements of electrochemical impedance studies to be led on large FC generators made of numerous individual cells. Moreover, new voltammetry protocols dedicated to PEMFC stack analysis are described. They enable for instance the study of membrane permeability and loss of platinum activity inside complete PEMFC assemblies. Keywords: PEMFC; Stack; Characterization; Electrochemical Impedance Spectroscopy; Cyclic Voltammetry; Linear Sweep Voltammetry
A distorted grid voltage or nonlinear behavior in the current control loop can cause low frequency current harmonics in a grid-connected voltage source inverter (VSI). Many efforts have been made to mitigate such phenomena, including hardware and/or control structure improvements. A well-known suitable strategy to reduce current harmonics in a selective manner is to apply a Proportional Multi-Resonant (PMR) current controller. Inverter-grid stability is another common issue when dealing with grid-connected VSI. Stability is influenced by the inverter impedance, which depends on the controller parameters. This paper presents a simplified tuning strategy for the PMR controller, taking into consideration the inverter-grid stability issue. The obtained controller was implemented and tested in a 10 kW three-phase inverter with a passively damped LCL filter. A significant reduction of current harmonics emission from the inverter up to 650 Hz was achieved without any hardware modification. The limits of PMR controllers to mitigate current harmonics were studied, and the influence of the grid impedance was verified.
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