Formamidinium lead triiodide (FAPbI 3 )-based perovskite materials are of interest for photovoltaics in view of their close-to-ideal bandgap, allowing absorption of photons over a broad solar spectrum. However, FAPbI 3 -based materials suffer from a notorious phase transition from the photoactive black phase (α-FAPbI 3 ) to nonperovskite yellow phase (δ-FAPbI 3 ) under ambient conditions. This transition dramatically reduces light absorbtion, thus, degrading the photovoltaic performance and stability of ensuring solar cells. In this study, 1-hexyl-3-methylimidazolium iodide (HMII) ionic liquid (IL) is employed as an additive for the first time in FAPbI 3 perovskite to overcome the above-mentioned issues. HMII incorporation facilitates the grain coarsening of FAPbI 3 crystal owing to its high-polarity and high-boiling point, which yields liquid domains between neighboring grains to reduce the activation energy of the grain-boundary migration. As a result, the FAPbI 3 active layer exhibits micronsized grains with substantially suppressed parasitic traps with an Urbach energy reduced by 2 meV. Hence, the resulting perovskite solar cell achieves an efficiency of 20.6% with notable increase in open circuit voltage (V OC ) of 80 mV compared with HMII-free cells (17.1%). More importantly, the HMIIdoped FAPbI 3 -based cells show a striking enhancement in shelf-stability under high humidity and thermal stress, retaining >80% of their initial efficiencies at 60 ± 10% relative humidity and ≈95% at 65 °C.
Despite the excellent photovoltaic performances of perovskite solar cells (PSCs), the instability of PSCs under severe environment (e.g. humidity, light-induced, etc.) limits further commercialization of such devices. Therefore, in recent years, research on the long-term stability improvement of PSCs has been actively carried out in perovskite field. To address these issues, we demonstrated the incorporation of ultra-thin interfacial layer of inorganic CsPbBr 1.85 I 1.15 perovskite quantum-dots (PQDs) that can effectively passivate defects at or near to the perovskite/hole transport material (HTM) interface, significantly suppressing interfacial recombination. This passivation layer increased the open circuit voltage (V oc ) of triple-cation perovskite cells by as much as 50 mV, with champion cells achieving V oc ∼ 1.14 V. As a result, we obtained hysteresis-free cells with the efficiency beyond 21%. More importantly, devices based on such architecture are capable of resisting humidity and lightinduced. Remarkably, the device employing CsPbBr 1.85 I 1.15 demonstrated a superb shelf-stability aganist to humidity under ambient conditions (R.H.≥40%), retaining nearly 91% of initial efficiency after 30 days, while the efficiency of control device rapidly dropped to 45% from its initial value under the same conditions. Besides benefiting from the high moisture resistivity as well as supressed ion migration, PSCs based on PQDs showed better operational stability (retaining 94% of their initial performance) than that of the PQDs-free one under continuous light irradiation over 400 h. In addition, a faster PL decay time of 4.66 ns was attained for perovskite/PQDs structure (5.77 ns for only PQDs structure) due to the favorable energy transfer at the interface, indicating a Förster resonance energy transfer (FRET) mechanism. This work indicates that inorganic PQDs are important materials as interlayer in PSCs to supremely enhance the device stability and efficiency.
The regular architecture (n-i-p) of perovskite solar
cells (PSCs)
has attracted increasing interest in the renewable energy field, owing
to high certified efficiencies in the recent years. However, there
are still serious obstacles of PSCs associated with spiro-OMeTAD hole
transport material (HTM), such as (i) prohibitively expensive material
cost (∼150–500 $/g) and (ii) operational instability
at elevated temperatures and high humidity levels. Herein, we have
reported the highly photo, thermal, and moisture-stable and cost-effective
PSCs employing inorganic CuFeO2 delafossite nanoparticles
as a HTM layer, for the first time. By exhibiting superior hole mobility
and additive-free nature, the best-performing cell achieved a power
conversion efficiency (PCE) of 15.6% with a negligible hysteresis.
Despite exhibiting a lower PCE as compared to the spiro-OMeTAD-based
control cell (19.1%), nonencapsulated CuFeO2-based cells
maintained above 85% of their initial efficiency, while the PCE of
control cells dropped to ∼10% under continuous illumination
at maximum power point tracking after 1000 h. More importantly, the
performance of control cells was quickly degraded at above 70 °C,
whereas CuFeO2-based cells, retaining ∼80% of their
initial efficiency after 200 h, were highly stable even at 85 °C
in ambient air under dark conditions. Besides showing significant
improvement in stability against light soaking and thermal stress,
CuFeO2-based cells exhibited superior shelf stability even
at 80 ± 5% relative humidity and retained over 90% of their initial
PCE. Overall, we strongly believe that this study highlights the potential
of inorganic HTMs for the commercial deployment of long-term stable
and low-cost PSCs.
Herein, the long‐term stability of vacuum‐deposited methylammonium lead iodide (MAPbI3) perovskite solar cells (PSCs) with power conversion efficiencies (PCEs) of around 19% is evaluated. A low‐temperature atomic layer deposition (ALD) Al2O3 coating is developed and used to protect the MAPbI3 layers and the solar cells from environmental agents. The ALD encapsulation enables the MAPbI3 to be exposed to temperatures as high as 150 °C for several hours without change in color. It also improves the thermal stability of the solar cells, which maintain 80% of the initial PCEs after aging for ≈40 and 37 days at 65 and 85 °C, respectively. However, room‐temperature operation of the solar cells under 1 sun illumination leads to a loss of 20% of their initial PCE in 230 h. Due to the very thin ALD Al2O3 encapsulation, X‐ray diffraction can be performed on the MAPbI3 films and completed solar cells before and after the different stress conditions. Surprisingly, it is found that the main effect of light soaking and thermal stress is a crystal reorientation with respect to the substrate from (002) to (202) of the perovskite layer, and that this reorientation is accelerated under illumination.
A new and promising dye-sensitized solar cell (DSSC) bilayer design was developed using an Fe2+/Fe3+ (ferrocene) liquid electrolyte and natural dyes extracted from Hypericum perforatum, Rubia tinctorum L. and Reseda luteola. The photovoltaic parameters controlling the device performance were then investigated. A DSSC based on quercetin dye displayed the most efficient solar to electricity conversion efficiency compared with other dyes with a maximum η value of 2.17%. Maximum overall conversion efficiencies under simulated sunlight that was comparable to natural photosynthesis were increased by 15%. The identification of appropriate additives for improving V
OC without causing dye degradation may result in further enhancement of cell performance, making the practical application of such systems more suitable for achieving economically viable solar energy devices.
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