The drying kinetics of a porous medium is classically described in three main periods, which depend on the interplay between the external and internal mass transfers during evaporation. The first period is described as essentially depending on the external mass transfer, whereas the third period is dominated by the internal mass transfer. The second period is a crossover period. We show experimentally that a similar drying kinetics can be obtained from a much simpler system owing to the effect of corner liquid films: a capillary tube of square cross section.

A new experimental setup for flow rate measurement of gases through microsystems is presented. Its principle is based on two complementary techniques, called droplet tracking method and constant-volume method. Experimental data on helium and argon isothermal flows through rectangular microchannels are presented and compared with computational results based on a continuum model with second-order boundary conditions and on the linearized kinetic BGK equation. A very good agreement is found between theory and experiment for both gases, assuming purely diffuse accommodation at the walls. Also, some experimental data for a binary mixture of monatomic gases are presented and compared with kinetic theory based on the McCormack model.

OATAO is an open access repository that collects the work of some Toulouse researchers and makes it freely available over the web where possible.

International audienceControl and understanding of flows inside fabricated nanochannels is rich in potential applications, but nanoscale physics of fluids remains to be clarified even for the simple case of spontaneous capillary filling. This paper reports an experimental and modelling investigation of the role of gas on the capillary filling kinetics slowdown in nanoslits (depth going from 20 nm to 400 nm) compared to Washburn's prediction. First, the role of gas through the usually observed trapped bubbles during a nanoslits capillary filling is analysed thanks to experiments realized with water, ethanol and silicone oil in siliconglass nanochannels. Bubbles are trapped only when slit depth is below a liquid-dependent threshold. This is interpreted as possible contact line pinning strength varying with wettability. Stagnant trapped bubbles lifetime is investigated for the three liquids used. Experimental results show that bubbles are first compressed because of the increasing local liquid pressure. Once the gas bubble pressure is sufficiently high, gas dissolution induces the final bubble collapse. Influence of the bubbles' presence on the capillary filling kinetics is analysed by estimating viscous resistance induced by the bubbles using an effective medium approach (Brinkman approximation). Surprisingly, the bubbles' presence is found to have a very minor effect on nanoslits capillary filling kinetics. Second, the transient gas pressure profile between the advancing meniscus and the channel exit is computed numerically taking into account gas compressibility. A non-negligible over-pressure ahead of the meniscus is found for nano-scale slit capillary filling. Considering the possible presence of precursor films, reducing cross-section for gas flow, leads to a capillary filling kinetics slowdown comparable to the ones measured experimentally

Salt crusts forming at the surface of a porous medium can dynamically evolve with crust displacements leading to the formations of domes and blisters or simply to the upward migration of the crust. However, the mechanisms explaining the displacements are unclear. It has been conjectured that they could be related to dissolutionprecipitation phenomena and/or to mechanical effects associated with the concept of crystallization pressure. We present a simple experiment where the crust upward migration is significant and can be entirely explained from the consideration of dissolution-precipitation phenomena. Equations governing the crust displacement are derived, leading to quite good agreement with the experimental results.

The diffusive and viscous leaks through a model spiral groove static ring gasket are studied analytically. This system is characterized by a transition from a leak through radial passages to a leak following the spiral groove as the load increases. The study concentrates on the transition. The results indicate a sharp (“critical”) transition with variations of several order of magnitudes in the leak flow rates for small changes in the contact area, i.e. the applied load. It is also shown how results for a diffusive leak and a viscous leak can be combined for identifying the transition. The influence of surface errors of form (waviness) is also considered. Although generally detrimental to tightness, it is however shown that errors of form could be beneficial to tightness for the high loads if their amplitudes are slightly smaller than the groove average depth.

Wicking and evaporation of volatile liquids in porous, cylindrical wicks is investigated where the goal is to model, using simple analytical expressions, the effects of variation in geometrical parameters of a wick, such as porosity, height and bead‐size, on the wicking and evaporation processes, and find optimum design conditions. An analytical sharp‐front flow model involving the single‐phase Darcy's law is combined with analytical expressions for the capillary suction pressure and wick permeability to yield a novel analytical approach for optimizing wick parameters. First, the optimum bead‐radius and porosity maximizing the wicking flow‐rate are estimated. Later, after combining the wicking model with evaporation from the wick‐top, the allowable ranges of bead‐radius, height and porosity for ensuring full saturation of the wick are calculated. The analytical results are demonstrated using some highly volatile alkanes in a polycarbonate sintered wick. © 2014 American Institute of Chemical Engineers AIChE J, 60: 1930–1940, 2014

Two-and three-dimensional creeping flows and diffusion transport through constricted and possibly rough surfaces are studied. Asymptotic expansions of conductances are derived as functions of the constriction local geometry. The validity range of the proposed theoretical approximations is explored through a comparison either with available exact results for specific two-dimensional aperture fields or with direct numerical computations for general three-dimensional geometries. The large validity range of the analytical expressions proposed for the hydraulic conductivity ͑and to a lesser extent for the electrical conductivity͒ opens up interesting perspectives for the simulation of flows in highly complicated geometries with a large number of constrictions.