Presently, there is increased attention and focus on heavy metals, which are becoming one of the most serious environmental problems due to their adverse health effects. These toxic heavy metals are not easily degraded and require removal from polluted water to protect people and the environment. The purpose of this work was to prepare two types of dithiocarbamate ligands, one aliphatic (diethyldithiocarbamate) and the other aromatic (diphenyldithiocarbamate), and to use them as chelators to remove Pb, Cd, Cu and Zn from polluted water. Dithiocarbamates were selected because they have good binding ability and can precipitate metal ions as complexes.The metal removal efficiency is compared between both ligands and also compared to the efficiency of activated carbon in an adsorption process to remove the same metals.The investigation results indicated that the diphenyldithiocarbamate ligand was more efficient in removing the studied metals than the diethyldithiocarbamate analogues.Additionally, the metal removal efficiency of the diphenyldithiocarbamate ligand was more effective than using the activated carbon method.

In this paper, a Schiff base ligand 1-(2-thiophenylimino)-4-(N-dimethyl)benzene (SL1) bearing azomethine (>C=N-) and thiol (-SH) moieties capable of coordinating to metals and forming colored metal complexes was synthesized and examined as a colorimetric chemosensor. The sensing ability toward the metal ions of Cu2+, Cr3+, Fe2+ Ni2+, Co2+, Mg2+, Zn2+, Fe2+, Fe3+, NH4VO3 (V5+), Mn2+, Hg2+, Pb2+, and Al3+ was investigated in a mixture of H2O and dimethylformamide (DMF) solvent using the UV–Visible spectra monitoring method. The synthesized Schiff base ligand showed colorimetric properties with Cr3+, Fe2+, Fe3+, and Hg2+ ions, resulting in a different color change for each metal that could be identified easily with the naked eye. The UV–Vis spectra indicated a significant red shift (~69–288 nm) from the origin after the addition of the ligand to these metal ions, which may be due to ligand-to-metal charge-transfer (LMCT). On applying Job’s plot, it was indicated that the ligand binds to the metal ions in a 2:1 ligand-to-metal molar ratio. SL1 behaves as a bidentate ligand and binds through the N atom of the imine group and the S atom of the thiol group. The results indicate that the SL1 ligand is an appropriate coordination entity and can be developed for use as a chemosensor for the detection of Cr3+, Fe2+, Fe3+, and Hg2+ ions.

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This investigation aimed at evaluating the efficiency of micro and nanoclays as a low-cost material for the removal of crystal violet (CV) dye from an aqueous solution. The impacts of various factors (contact time, pH, adsorbent dosage, temperature, initial dye concentration) on the adsorption process have been taken into consideration. Six micro and nanoclay samples were obtained by treating clay materials collected from different locations in the Albaha region, Saudi Arabia. Out of the six tested micro and nanoclays materials, two (NCQ1 and NCQ3) were selected based on the highest adsorption efficiency for complete experimentation. The morphology and structure of the selected micro and nanoclay adsorbents were characterized by various techniques: SEM-EDX, FTIR, XRF, XRD, and ICP-MS. The XRF showed that the main oxides of both nanoclays were SiO2, Al2O3, Fe2O3, K2O, CaO, and MgO, and the rest were impurities. All the parameters affecting the adsorption of CV dye were optimized in a batch system, and the optimized working conditions were an equilibrium time of 120 min, a dose of 30 mg, a temperature of 25 °C, and an initial CV concentration of 400 mg/L. The equilibrium data were tested using nonlinear isotherm and kinetic models, which showed that the Freundlich isotherm and pseudo-second-order kinetics gave the best fit with the experimental data, indicating a physico-chemical interaction occurred between the CV dye and both selected micro and nanoclay surfaces. The maximum adsorption capacities of NCQ1 and NCQ3 adsorbents were 206.73 and 203.66 mg/g, respectively, at 25 °C. The thermodynamic factors revealed that the CV dye adsorption of both micro and nanoclays was spontaneous and showed an exothermic process. Therefore, the examined natural micro and nanoclays adsorbents are promising effective adsorbents for the elimination of CV dye from an aqueous environment.

AbstractThe purpose of this work was to prepare Schiff base ligands containing quinoline moiety and using them for preparing Cu(ii) and Zn(ii) complexes. Four bidentate Schiff base ligands (SL1–SL4) with quinoline hydrazine scaffold and a series of mononuclear Cu(ii) and Zn(ii) complexes were successfully prepared and characterized. The in vitro antibacterial and antifungal potential experimentation revealed that the ligands exhibited moderate antibacterial activity against the Gram-positive bacterial types and were inactive against the Gram-negative bacteria and the fungus strains. The metal complexes showed some enhancement in the activity against the Gram-positive bacterial strains and were inactive against the Gram-negative bacteria and the fungus strains similar to the parent ligands. The complex [Cu(SL1)2] was the most toxic compound against both Gram-positive S. aureus and E. faecalis bacteria. The in silico physicochemical investigation revealed that the ligand SL4 showed highest in silico absorption (82.61%) and the two complexes [Cu(SL4)2] and [Zn(SL4)2] showed highest in silico absorption with 56.23% for both compounds. The in silico pharmacokinetics predictions showed that the ligands have high gastrointestinal (GI) absorption and the complexes showed low GI absorption. The ligands showed a good bioavailability score of 0.55 where the complexes showed moderate to poor bioavailability.

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Vanadium complexes containing Schiff base ligands are of great importance and have numerous applications. A series of Schiff base ligands derived from 4-amino-5-mercapto-3phenyl-1,2,4-triazole and different aldehydes were synthesized and combined with ammonium metavanadate in 2:1 and 1:1 molar ration to yield oxo-and dioxo-vanadium(V) complexes NH4[VO(La-f)2] and NH4[VO2(Lg-h)2], respectively. The structure of the synthesized compounds was confirmed by elemental analysis, UV, IR, NMR, MS and TGA. Complexes with bidentate and tridentate ligands were expected to possess a distorted square-pyramidal structure. The ligands and their complexes have been examined for antimicrobial activity against six types of bacteria and one kind of fungus that widely distributed in Albaha region, Kingdom of Saudi Arabia. The results indicate that some of the complexes were active against C. albicans fungus when used as powder, and no sound activity were shown against any type of tested bacteria.