Graphene-like materials have attracted significant attention as alternative catalyst carriers due to the broad possibilities of changing their shape, composition, and properties. In this study we investigated the structural and electrochemical characteristics of platinum electrocatalysts supported on reduced graphene oxide (rGO), including those modified with amine functionalities, nitrogen heteroatoms (rGO-Am), and oxygen enriched (rGO-O). Synthesis of Pt nanoparticles (20 wt.%) on the graphene-like nanomaterials surface was carried out using a modified polyol procedure. The Pt20/rGO-Am showed a lower Pt nanoparticles size together with high Pt utilization and EASA values compared to rGO-supported catalysts and the Pt/C reference sample due to the uniform distribution of nucleation centers on the surface of graphene nanoparticles, and the greater ability of these centers to electrically bond with platinum.
The comparative study of electrocatalysts synthesized by chemical reduction and pulsed magnetron-ion sputtering for polymer electrolyte membrane electrochemical systems are presented. Various carbon nanomaterials were used as supports of Pt nanoparticles: carbon black, nanotubes, nanofibers and reduced graphene oxide. The electrochemical studies of the obtained electrocatalysts as well as their testing in the fuel cell membrane-electrode assembly were carried out. The influence of supports morphology and the deposition approach of Pt nanoparticles on the electrochemically active surface area and activity of electrocatalysts, as well as the prospects of the magnetron-ion sputtering approach for electrocatalysts synthesis were studied and discussed.
In the present work the activity and stability of the IrOx/TiOx catalyst obtained by the polyol approach in the oxygen evolution reaction (OER) were studied in comparison with the commercial analogue IrOx. Electrochemical studies were provided, including accelerated stress testing. The synthesized IrOx/TiOx catalyst demonstrated higher OER activity and stability than the commercial IrOx, and the obtained results allow to suggest and discuss possible mechanisms of the studied catalysts degradation. Tests of membrane-electrode assemblies based on synthesized IrOx/TiOx catalysts in SPE water electrolyzer demonstrate the possibility to significantly reduce the noble metal content on the anode..
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