Novel environment-friendly NaNbO3-based lead-free ceramics with ultrahigh energy storage density and power density for multilayer ceramic capacitor applications.
Major polyphenolic compounds in pineapple peels were identified and quantified. The antioxidant capacities of pineapple peel extracts and these polyphenolic compounds were determined using DPPH q scavenging capacity and phosphomolybdenum method. Effects of these polyphenolics' interactions on their antioxidant capacity were also evaluated. Gallic acid (31.76 mg/100 g dry extracts), catechin (58.51 mg/100 g), epicatechin (50.00 mg/100 g), and ferulic acid (19.50 mg/100 g) were found to be the main polyphenolics in pineapple peels. The IC 50 for DPPH q scavenging assay of the extracts was 1.13 mg/ml and total antioxidant capacity was 0.037 g ascorbic acid equivalents/g. The order of DPPH q scavenging capacity of per mole of these polyphenolic compounds present in pineapple peels was gallic acid > epicatechin = catechin > ferulic acid, but it was different when using phosphomolybdenum method the order of which was epicatechin. > catechin > gallic acid = ferulic acid. Results of polyphenolics' interactions indicated no synergistic effects. In the combinations of ferulic acid-epicatechin and ferulic acid-gallic acid, additive effects were found using both antioxidant activity assays.
Recently, ceramic capacitors with
fast charge–discharge
performance and excellent energy storage characteristics have received
considerable attention. Novel NaNbO3-based lead-free ceramics
(0.80NaNbO3-0.20SrTiO3, abbreviated as 0.80NN-0.20ST),
featuring ultrahigh energy storage density, ultrahigh power density,
and ultrafast discharge performance, were designed and prepared in
this study. These 0.80NN-0.20ST ceramics exhibited a high breakdown
strength of 323 kV/cm, attributable to their small grain size and
dense microstructure, a recoverable energy storage density of 3.02
J/cm3, and an energy storage efficiency of 80.7% at an
applied electric field of 310 kV/cm. The excellent stability of energy
storage properties in frequency (0.1–1000 Hz), temperature
(20–120 °C), and fatigue resistance (cycle number: 105) were also observed in the 0.80NN-0.20ST ceramics. In contrast
with other recently reported lead-free ceramic-based dielectric capacitors,
the 0.80NN-0.20ST ceramics display a high energy storage efficiency
combined with a high recoverable energy storage density, which indicates
that they have wide application foreground and potential in the field
of energy storage. These ceramics also show a considerable current
density of 677 A/cm2, an ultrahigh power density of 23.7
MW/cm3, and a short release duration (∼225 ns).
This study brings the NaNbO3-based ceramics into a new
chapter of research and application of energy storage dielectric capacitors.
Previous studies have shown that multivesicular bodies (MVBs)/endosomes-mediated vesicular trafficking may play key roles in plant immunity and cell death. However, the molecular regulation is poorly understood in rice. Here we report the identification and characterization of a MVBs-localized AAA ATPase LRD6-6 in rice. Disruption of LRD6-6 leads to enhanced immunity and cell death in rice. The ATPase activity and homo-dimerization of LRD6-6 is essential for its regulation on plant immunity and cell death. An ATPase inactive mutation (LRD6-6E315Q) leads to dominant-negative inhibition in plants. The LRD6-6 protein co-localizes with the MVBs marker protein RabF1/ARA6 and interacts with ESCRT-III components OsSNF7 and OsVPS2. Further analysis reveals that LRD6-6 is required for MVBs-mediated vesicular trafficking and inhibits the biosynthesis of antimicrobial compounds. Collectively, our study shows that the AAA ATPase LRD6-6 inhibits plant immunity and cell death most likely through modulating MVBs-mediated vesicular trafficking in rice.
Shape
memory polymers (SMPs), as a class of intelligent materials,
have shown great potential in biomedical and robotic fields. Although
efforts have been made to design and fabricate SMPs in the past decades,
most of the SMPs are not suitable for use in the human body due to
their unpleasant triggering conditions. Furthermore, it is of great
importance to diversify the shape memory effect (SME) of SMPs to extend
their applications. In this work, through thiol-ene chemistry, SMPs
based on random cross-linked hydrophobic polytetrahydrofuran (PTHF)
and hydrophilic poly(ethylene glycol) (PEG) oligomers were facilely
fabricated. These SMPs showed a body temperature-triggered two-way
SME with a reversible strain of up to 25.2%. Besides, the SMPs exhibited
a good body temperature- and water-triggered one-way triple-SME. These
features bestowed the polymers with a bright future in biomedical
applications. Polymer P60-G40 was applied as a new type of esophageal
stent, and the in vitro assessment showed that the stent was adjustable,
self-expandable, and had the ability to release drugs, which were
attributed to the one-way triple-SME and two-way SME.
Shape memory hydrogels, a promising class of smart materials for biomedical applications, have attracted increasing research attention owing to their tissue-like water-rich network structure. However, preparing shape memory hydrogels with high mechanical strength and body temperature-responsiveness has proven to be an extreme challenge. This study presents a facile and scalable methodology to prepare highly tough hydrogels with body temperature-responsive shape memory effect based on synergetic hydrophobic interactions and hydrogen bonding. 2phenoxyethyl acrylate (PEA) and acrylamide (AAm) were chosen as hydrophobic monomer and hydrophilic hydrogen bonding monomer, respectively. The prepared hydrogels exhibited a maximum tensile strength of 5.1±0.16 MPa with satisfactory stretchability, and the mechanical strength showed a strong dependence on temperature. Besides, the hydrogel with 60 mol% PEA shows an excellent body temperature-responsive shape memory behavior with almost 100% shape fixity and shape recovery. Furthermore, we applied the hydrogels as shape memory embolization plug for simulating vascular occlusion, and the embolism performance was preliminarily explored in vitro.
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