In submarines, machinery with reciprocating rotating parts is placed on rubber mountings to isolate noise and vibration from the hull of the vessel. Otherwise the hull would radiate the noise to the sea and facilitate detection of the submarine by the enemy. The dynamic mechanical properties of the rubber in the mountings determine to a large extent their effectiveness in isolating noise and vibration. Only within the last ten years has reliable information become available on the dynamic mechanical properties of rubber at high frequencies of vibration. Most of this advance has been due to Nolle. Other workers in this field have been Witte, Mrowca and Guth, Hillier, Cramer and Silver, and Morris, James and Snyder. Nolle gave an excellent description and analysis of techniques for measuring the dynamic mechanical properties of rubber in the frequency range of 0.1 to 120,000 cycles per second (cps). The methods which he described were identified as rocking-beam oscillator, vibrating reed, strip transmission, strip resonance, and magnetostriction. Guth and associates, Hillier, and Cramer and Silver used the strip transmission method in their respective investigations. Morris, James, and Snyder used a bar transmission method which had not been previously described. This paper deals with a modification of the bar transmission method, whereby the resonant frequency and dispersion of the vibrational energy above and below the resonant frequency are measured. From this information the velocity of sound, Young's modulus, and loss factor of the rubber are calculated.
Information on the relative rates of cure of GR-S stocks and similar Hevea stocks in thick sections is of interest to many rubber manufacturers. Since curing conditions for thick articles from Hevea stocks have been established, they would like to know how these conditions must be altered when GR-S stocks are used in the same applications. They could develop a GR-S stock with the same rate of cure as the Hevea stock which it replaces according to laboratory tests on comparatively thin sheets, but this agreement does not mean necessarily that thick sections cure at the same rate. The respective rates of heat flow through the rubbers must be considered. Only if the rates of heat flow as well as the curing rates of thin sections are in agreement, will the curing rates of the thick sections be equal. Juve and Garvey found that GR-S tread stocks cure faster in the center of thick sections than similar Hevea tread stocks. They were unable to explain this behavior because, according to their measurements, the thermal conductivity of the GR-S tread stock was less, and its specific heat greater than, the corresponding values for the Hevea tread stock. They concluded that the difference mav be due to an exothermic reaction.
A survey has been made of hard GR-S with regard to sulfur requirement and effects of various pigments, softeners, and accelerators on tensile strength, ultimate elongation, hardness, and stiffness. Of particular interest where the observations that hard GR-S had a higher tensile strength than hard Hevea rubber, and that hard GR-S did not undergo much loss in tensile strength when compounded with 60 volumes of channel black or semi-reinforcing black.
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