We report 30-nm-gate-length InAlN/AlN/GaN/SiC high-electron-mobility transistors (HEMTs) with a record current gain cutoff frequency (f T ) of 370 GHz. The HEMT without back barrier exhibits an extrinsic transconductance (g m.ext ) of 650 mS/mm and an on/off current ratio of 10 6 owing to the incorporation of dielectric-free passivation and regrown ohmic contacts with a contact resistance of 0.16 Ω · mm. Delay analysis suggests that the high f T is a result of low gate-drain parasitics associated with the rectangular gate. Although it appears possible to reach 500-GHz f T by further reducing the gate length, it is imperative to investigate alternative structures that offer higher mobility/velocity while keeping the best possible electrostatic control in ultrascaled geometry.
Nonaqueous
rechargeable lithium–oxygen batteries (LOBs)
are one of the most promising candidates for future electric vehicles
and wearable/flexible electronics. However, their development is severely
hindered by the sluggish kinetics of the ORR and OER during the discharge
and charge processes. Here, we employ MOF-assisted spatial confinement
and ionic substitution strategies to synthesize Ru single atoms riveted
with nitrogen-doped porous carbon (Ru SAs-NC) as the electrocatalytic
material. By using the optimized Ru0.3 SAs-NC as electrocatalyst
in the oxygen-breathing electrodes, the developed LOB can deliver
the lowest overpotential of only 0.55 V at 0.02 mA cm–2. Moreover, in-situ DEMS results quantify that the e–/O2 ratio of LOBs in a full cycle is only 2.14, indicating
a superior electrocatalytic performance in LOB applications. Theoretical
calculations reveal that the Ru–N4 serves as the
driving force center, and the amount of this configuration can significantly
affect the internal affinity of intermediate species. The rate-limiting
step of the ORR on the catalyst surface is the occurrence of 2e– reactions to generate Li2O2,
while that of the OER pathway is the oxidation of Li2O2. This work broadens the field of vision for the design of
single-site high-efficiency catalysts with maximum atomic utilization
efficiency for LOBs.
3D macroscopic tin oxide/nitrogen-doped graphene frameworks (SnO2/GN) were constructed by a novel solvothermal-induced self-assembly process, using SnO2 colloid as precursor (crystal size of 3-7 nm). Solvothermal treatment played a key role as N,N-dimethylmethanamide (DMF) acted both as reducing reagent and nitrogen source, requiring no additional nitrogen-containing precursors or post-treatment. The SnO2/GN exhibited a 3D hierarchical porous architecture with a large surface area (336 m(2)g(-1)), which not only effectively prevented the agglomeration of SnO2 but also facilitated fast ion and electron transport through 3D pathways. As a result, the optimized electrode with GN content of 44.23% exhibited superior rate capability (1126, 855, and 614 mAh g(-1) at 1000, 3000, and 6000 mA g(-1), respectively) and extraordinary prolonged cycling stability at high current densities (905 mAh g(-1) after 1000 cycles at 2000 mA g(-1)). Electrochemical impedance spectroscopy (EIS) and morphological study demonstrated the enhanced electrochemical reactivity and good structural stability of the electrode.
In vivo MEO2 MA@MEO2 MA-co-OEGMA-CuS-DOX (G-CuS-DOX) nanocapsules increase the temperature of tumors from room temperature to 57 °C due to the photothermal effect under irradiation from a 915-nm laser. When the temperature exceeds 42 °C, photothermal therapy of G-CuS-DOX is switched on. Simultaneously, higher temperatures (>LCST, 42 °C) induce volume shrinkage of G-CuS-DOX in vivo, leading to the controllable release of the anticancer drug DOX. If the NIR laser is switched off, both therapy effects are interrupted immediately.
Flexible free-standing hollow Fe 3 O 4 /graphene (H-Fe 3 O 4 /GS) films were fabricated through vacuum filtration and thermal reduction processes, in which graphene formed a three-dimensional conductive network, with hollow and porous Fe 3 O 4 spindles being captured and distributed homogeneously. Using the films as binder-free and free-standing electrodes for lithium-ion batteries, H-Fe 3 O 4 /GS with 39.6 wt % graphene exhibited a high specific capacity (1555 mA h g À1 at 100 mA g À1 ), enhanced rate capability and excellent cyclic stability (940 and 660 mA h g À1 at 200 and 500 mA g À1 after 50 cycles, respectively). The superior electrochemical performance of this novel material can be attributed to two factors. One is that the three dimensional (3D) graphene network formed is very helpful for keeping H-Fe 3 O 4 in good electrical contact. Another is the short transport length for both lithium ions and electrons due to the porous nature which accommodates volume change and favors electrolyte penetration. It is believed that the strategy for preparing free-standing H-Fe 3 O 4 /GS films presented in this work will provide new insight into the design and synthesis of other metal oxide/GS electrodes for flexible energy storage devices.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations –citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.