Tunneling and chemical reactions by tunneling switching are reported for phenol and ortho-deuterophenol on the basis of high-resolution FTIR spectroscopy. Tunneling splittings are measured for the torsional motion in the ground and several vibrationally excited states of phenol. Tunneling times range from 10 ns to 1 ps, depending on excitation. For more-highly excited torsional levels in ortho-deuterophenol, delocalization and chemical reaction by tunneling switching is found.
There are strong reasons to believe that our conscious inner life is structured, suggested both by introspection as well as scientific psychology. One of the most salient structural characteristics of conscious experiences is known as unity of consciousness. In this contribution, we wish to demonstrate how features of experience that pertain to the unity of consciousness could be made precise in terms of mathematical relations that hold between phenomenal objects.Based on phenomenological considerations, we first outline three such features. These are (i) environmental embedding, (ii) the mutual constraint between local and global representations, and (iii) a top-down process of object formation in consciousness. We then introduce a formal model based on the notion of phenomenal space, defined in terms of a set of quasi-elementary and extended entities. We describe the structure of phenomenal space by appealing to mereological and topological concepts, and we outline a projector-based calculus to account for the idea that the structure of phenomenal space is ultimately dynamical.Using the above concepts, one could approach the mind-matter problem by relating environmentally embedded agents to the topologically well-defined objects that result from decompositions of phenomenal space. We conclude our discussion by putting it into the context of some recent theoretical questions that appear in cognitive science and consciousness studies. We opt for the possibility to regard the phenomenon of consciousness not in terms of a singular transition that happens between "brain" and "mind" but rather in terms of a series of transitions between structured layers of experience.
Models of consciousness aim to inspire new experimental protocols and aid interpretation of empirical evidence to reveal the structure of conscious experience. Nevertheless, no current model is univocally accepted on either theoretical or empirical grounds. Moreover, a straightforward comparison is difficult for conceptual reasons. In particular, we argue that different models explicitly or implicitly subscribe to different notions of what constitutes a satisfactory explanation, use different tools in their explanatory endeavours and even aim to explain very different phenomena. We thus present a framework to compare existing models in the field with respect to what we call their ‘explanatory profiles’. We focus on the following minimal dimensions: mode of explanation, mechanisms of explanation and target of explanation. We also discuss the empirical consequences of the discussed discrepancies among models. This approach may eventually lead to identifying driving assumptions, theoretical commitments, experimental predictions and a better design of future testing experiments. Finally, our conclusion points to more integrative theoretical research, where axiomatic models may play a critical role in solving current theoretical and experimental contradictions.
A theory of consciousness, whatever else it may do, must address the structure of experience. Our perceptual experiences are richly structured. Simply seeing a red apple, swaying between green leaves on a stout tree, involves symmetries, geometries, orders, topologies, and algebras of events. Are these structures also present in the world, fully independent of their observation? Perceptual theorists of many persuasions—from computational to radical embodied—say yes: perception veridically presents to observers structures that exist in an observer-independent world; and it does so because natural selection shapes perceptual systems to be increasingly veridical. Here we study four structures: total orders, permutation groups, cyclic groups, and measurable spaces. We ask whether the payoff functions that drive evolution by natural selection are homomorphisms of these structures. We prove, in each case, that generically the answer is no: as the number of world states and payoff values go to infinity, the probability that a payoff function is a homomorphism goes to zero. We conclude that natural selection almost surely shapes perceptions of these structures to be non-veridical. This is consistent with the interface theory of perception, which claims that natural selection shapes perceptual systems not to provide veridical perceptions, but to serve as species-specific interfaces that guide adaptive behavior. Our results present a constraint for any theory of consciousness which assumes that structure in perceptual experience is shaped by natural selection.
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