All existing transistors are based on the use of semiconductor junctions formed by introducing dopant atoms into the semiconductor material. As the distance between junctions in modern devices drops below 10 nm, extraordinarily high doping concentration gradients become necessary. Because of the laws of diffusion and the statistical nature of the distribution of the doping atoms, such junctions represent an increasingly difficult fabrication challenge for the semiconductor industry. Here, we propose and demonstrate a new type of transistor in which there are no junctions and no doping concentration gradients. These devices have full CMOS functionality and are made using silicon nanowires. They have near-ideal subthreshold slope, extremely low leakage currents, and less degradation of mobility with gate voltage and temperature than classical transistors.

Ocean colour data from the NASA Seaviewing Wide Field-of-view Sensor (SeaWiFS) was used to estimate chlorophyll a concentration around New Zealand on a monthly basis between September 1997 and May 2000. The performance of the SeaWiFS chlorophyll a algorithm (OC4v4) was investigated by comparing in situ measurements of the underwater light field with measurements of phytoplankton pigment concentration by High Performance Liquid Chromatography. The algorithm performed well for chlorophyll a concentrations below 0.6 mg m-3 but overestimated by a factor of two or more at higher concentrations. The average chlorophyll a concentration for New Zealand Exclusive Economic Zone was calculated as an indication of the overall productivity of the region and varied between 0.26 and 0.43 mg m-3 with no obvious relationship to the Southern Oscillation Index. New †

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Accurate estimation of the greenhouse gas (GHG) mitigation potential of bioenergy crops requires the integration of a significant component of spatially varying information. In particular, crop yield and soil carbon (C) stocks are variables which are generally soil type and climate dependent. Since gaseous emissions from soil C depend on current C stocks, which in turn are related to previous land management it is important to consider both previous and proposed future land use in any C accounting assessment. We have conducted a spatially explicit study for England and Wales, coupling empirical yield maps with the RothC soil C turnover model to simulate soil C dynamics. We estimate soil C changes under proposed planting of four bioenergy crops, Miscanthus (Miscanthus  giganteus), short rotation coppice (SRC) poplar (Populus trichocarpa Torr. & Gray  P. trichocarpa, var. Trichobel), winter wheat, and oilseed rape. This is then related to the former land use -arable, pasture, or forest/seminatural, and the outputs are then assessed in the context of a life cycle analysis (LCA) for each crop. By offsetting emissions from management under the previous land use, and considering fossil fuel C displaced, the GHG balance is estimated for each of the 12 land use change transitions associated with replacing arable, grassland, or forest/seminatural land, with each of the four bioenergy crops. Miscanthus and SRC are likely to have a mostly beneficial impact in reducing GHG emissions, while oilseed rape and winter wheat have either a net GHG cost, or only a marginal benefit. Previous land use is important and can make the difference between the bioenergy crop being beneficial or worse than the existing land use in terms of GHG balance.

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Intertidal ecosystems have primarily been studied using field-based sampling; remote sensing offers the ability to collect data over large areas in a snapshot of time that could complement field-based sampling methods by extrapolating them into the wider spatial and temporal context. Conventional remote sensing tools (such as satellite and aircraft imaging) provide data at limited spatial and temporal resolutions and relatively high costs for small-scale environmental science and ecologically-focussed studies. In this paper, we describe a low-cost, kite-based imaging system and photogrammetric/mapping procedure that was developed for constructing high-resolution, three-dimensional, multi-spectral terrain models of intertidal rocky shores. The processing procedure uses automatic image feature detection and matching, structure-from-motion and photo-textured terrain surface reconstruction algorithms that require minimal human input and only a small number of ground control points and allow the use of cheap, consumer-grade digital cameras. The resulting maps combine imagery at visible and near-infrared wavelengths and topographic information at sub-centimeter resolutions over an intertidal shoreline 200 m long, thus enabling spatial properties of the intertidal environment to be determined across a hierarchy of spatial scales. Results of the system are presented for an intertidal rocky shore at Jervis Bay, New South Wales, Australia. Potential uses of this technique include mapping of plant (micro- and macro-algae) and animal (e.g. gastropods) assemblages at multiple spatial and temporal scales.

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In this work, we report the fabrication and in-depth electrochemical analysis of discrete gold nanowire electrodes for use in electrochemical applications. The single nanowire electrodes were fabricated using a hybrid E-beam/photolithography approach at silicon substrates, providing electrodes with well-defined and reproducible dimensions. Following fabrication, nanowire devices were characterized by electrical and electrochemical techniques. Low electrical resistances with typical linear Ohmic responses were observed from fully packaged electrode devices. Finite element diffusion domain simulation studies were undertaken to explore analyte mass transport to nanowire electrodes at a variety of scan rates. Simulation results suggested that radial analyte diffusion profiles to nanoelectrodes should be present at fast scan rates. This behavior was confirmed experimentally where cyclic voltammograms obtained in ferrocenemonocarboxylic acid were observed to be steady-state, with high measurable currents (nA) and sigmoidal up to 1000 mV s −1 . Nanowire electrodes had very low capacitance, ∼ 37 ± 6 nF cm −2 per nanowire, 3 orders of magnitude lower than that typically achieved by ultramicroelectrodes. The electrochemical responses of nanowires, in model redox mediators, were excellently described by Butler−Volmer kinetics. The nanowire electrodes are applied to reproducible determination of heterogeneous electron transfer-rate constants, k 0 , for three key model redox analytes, FcCOOH, Fe(II)(CN) 6 4− , and Ru(NH 3 ) 6 3+ .