Levels of BTEX (benzene, toluene, ethylbenzene, and p-xylene) were determined in ambient air of an urban site located at the center of Mexico (Leon City in Guanajuato State) during two climatic seasons of 2018 (summer and autumn). Ethylbenzene (11.86 µg m−3) and toluene (11.85 µg m−3) showed the highest median concentrations during the study period. BTEX concentrations did not show a diurnal pattern but a seasonal trend was observed for benzene and toluene at a significant level of α = 0.05. Bi-variate and multivariate analysis showed significant positive correlations (at α = 0.05) among BTEX (excepting benzene), indicating common sources for toluene, ethylbenzene, and p-xylene and a different origin for benzene. A meteorological study was also conducted in order to determine the origin of air masses that could influence the BTEX concentrations in the study site. Finally, it was found that all BTEX species presented hazard quotient values (HQs) <1, indicating that there is no risk of non-cancer during the studied period. Lifetime cancer risk due to benzene exposure for the adult and child populations studied were estimated to be 7 in 1,000,000 and 1 in 100,000, respectively.
Short-term effects of air pollution on the health of residents in the Metropolitan Area of Monterrey, Mexico were assessed from 2012–2015 using a time-series approach. Guadalupe had the highest mean concentrations for SO2, CO and O3; whereas Santa Catarina showed the highest NO2 concentrations. Escobedo and Garcia registered the highest levels for PM10. Only PM10 and O3 exceeded the maximum permissible values established in the Mexican official standards. Most of pollutants and municipalities showed a great number of associations between an increase of 10% in their current concentrations and mortality, especially for people >60 years. Different scenarios resulting from climatic change were built (increases of 5–25% in daily mean temperature), but only the increase of 25% (5 °C) showed a significant association with air pollutant concentrations and mortality. All pollutants and municipalities showed significant increases in relative risk indexes (RRI) resulting from an increase of 5 °C when people >60 years was considered. Results were comparable to those reported by other authors around the world. The RRI were low but significant, and thus are of public concern. This study demonstrated that the elderly is strongly threatened not only by atmospheric pollution but also by climatic change scenarios in warm and semiarid places.
Trace metal concentrations in PM10 were measured in an urban–industrial site in León, Mexico in three different seasons. PM10 were collected in quartz fiber filters of 47 mm diameter using low volume equipment operating with a controlled flow of 5 L min−1 over 24 h. Mass concentrations were gravimetrically determined and it was found that PM10 samples showed values in excess of the Mexican standard and the established values by WHO during cold dry and warm dry seasons. Morphology of selected particles was studied by SEM-EDS analysis, and the elemental composition was determined. Collected samples were analyzed by atomic absorption spectrometry in order to quantify ambient air concentrations of some trace metals (Cu, Co, Zn, Cd, Fe, Mg, and Mn). Median concentrations of trace metals showed the maximum value for iron (3.079 μgm−3) and the minimum value for Cd (0.050 μgm−3) over the entire period. From the meteorological analysis, it was found that sources located SW and ESE of the sampling site contributed to the levels of trace metals in PM10 in the studied site. The health risk assessment found that the population of León is at increased lifetime risk of experiencing cancer because of exposure to these concentrations of PM10 and their trace metal content.
Short-term effects of air pollution on the number of hospital admissions in eight municipalities of the Metropolitan Area of Monterrey, Mexico, were assessed from 2016 to 2019 using a time-series approach. Air quality data were obtained from the Atmospheric Monitoring System of Nuevo Leon State (SIMA) which belongs to SINAICA (National System of Air Quality Information), providing validated data for this study. Epidemiological data were provided by SINAIS (National System of Health Information), considering admission by all causes and specific causes, gender and different age groups. Guadalupe had the highest mean concentrations for SO2, CO and O3; whereas Santa Catarina showed the highest NO2 concentrations. Escobedo and Garcia registered the highest levels for PM10. Only PM10 and O3 exceeded the permissible maximum values established in Mexican official standards. A basal Poisson model was constructed to assess the association between daily morbidity and air pollutants, from this, a second scenario in which daily mean concentrations of air pollutant criteria increase by 10% was considered. Most of pollutants and municipalities studied showed a great number of associations between an increase of 10% in their current concentrations and morbidity, especially for the age group between 5 and 59 years during cold months, excepting ozone which showed a strongest correlation during summer. Results were comparable to those reported by other authors around the world, however, in spite of relative risk index (RRI) values being low, they are of public concern. This study demonstrated that considering the nature of their activities, economically active population and students, they could be more vulnerable to air pollution effects. Results found in this study can be used by decision makers to develop public policies focused on protecting this specific group of the population in metropolitan areas in Mexico.
During 2020-2021, the COVID-19 pandemic resulted in a lockdown in many countries around the world. This work assessed the impact of the restrictions to economical and industrial activities, and population mobility on N and S atmospheric deposition fluxes in the Metropolitan Zone of Monterrey (MZM). Trends of atmospheric deposition fluxes were analyzed and compared during two periods. The first period before pandemic from 27 February 2017 to 15 October 2018; the second one, from 20 October 2020 to 5 May 2021. Both periods including two climatic seasons (dry and rainy) and considering the same sampling points along MZM. Passive collectors of throughfall deposition (hydrologic flux of ions to floor contained within a solution) were used to estimate concentrations for SO4 2and NO3-. From a meteorological analysis, by using back-air masses trajectories and wind roses, the influence on transport and deposition of pollutants was assessed. The results showed that the change rates of N and S before and during the lockdown ranged from 63%-67% and 90% for N and S, respectively. The response of S was more sensitive to the lockdown than N. Since, during pandemic, industrial and vehicular emissions, and forest fires were reduced; it had a positive impact on atmospheric deposition. However, besides the lockdown due to COVID-19, the observed changes in spatial and temporal deposition patterns also could be attributed to meteorological conditions associated to the sampling season, particularly to precipitation patterns. Mean atmospheric deposition fluxes for N and S for the two studied periods were compared with critical load values established for sensitive ecosystems in Europe. Exceedances to critical load values before pandemic were significant higher than those found for the period during pandemic, suggesting that the lockdown improved the air quality in MZM.
The objective of this study was to assess the spatial and temporal distribution of nitrogen and sulfur deposition and its relationship with meteorological conditions in the metropolitan area of León in Guanajuato, México. N and S atmospheric deposition was collected using passive samplers (IER) in 10 sites in León City during three climatic seasons in 2018. Nitrate, ammonium, and sulfate concentrations and deposition fluxes of N and S were determined. From wind and air-mass trajectories analysis, mechanisms and possible sources contributing to N and S deposition in the study area were assessed. Atmospheric deposition fluxes were compared to critical load values reported for sensitive ecosystems in Europe. It was found that mean deposition flux for N (5.82 Kg N ha −1 year −1) was within the range of values reported for sensitive ecosystems in Nuevo México, Europe, and California. On the other hand, the mean deposition flux for S (13.77 S Kg ha −1 year −1) exceeded the critical load values proposed for Europe, suggesting that current S deposition could be a risk for ecosystems and water bodies in the region.
A nova Escala de Paradigma Ecológico revisada (NEP-R) traduzida para o espanhol é um instrumento amplamente utilizado em vários países, culturas e populações para medir as crenças ambientais das pessoas. Dada a discrepância em sua dimensionalidade relatada em estudos anteriores e como não há relatos de suas propriedades psicométricas da escala NEP-R na população universitária mexicana, eles foram analisados. A escala foi aplicada a 503 estudantes da Universidade Autônoma do Carmen, de diferentes entidades federais do sudeste do México. A consistência interna (α de Cronbach) da escala NEP-R foi analisada e uma análise fatorial exploratória (AFE) com rotação varimax foi realizada. A descoberta revelou um ótimo coeficiente de consistência interna (α = 0,702) e uma estrutura de dois fatores (ecocentrismo e antropocentrismo), que juntos representam 43,272% da variância total em uma versão da escala de 9 itens. Concluise que a escala NEP.R é uma ferramenta útil. No entanto, é imperativo avaliar sua confiabilidade e dimensionalidade para diferentes populações-alvo.
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