Carbon nanotubes (CNTs) have outstanding properties that can be used to produce intelligent devices to detect pathogens, delivery drugs, and replace bone and dental parts. Therefore, CNTs have been extensively studied as medical devices.
A brief review reporting the recent advances on the carbon nanostructured materials-based sensors covering recently published works is presented. Several works dealing with experimental and theoretical data are reviewed and discussed. The main results for carbon nanotubes, nanodiamonds, fullerene, graphene, and hybrid carbon-nanostructured devices that show sensing properties in different fields were considered for the discussions. The goal of this paper was to highlight sensor mechanisms, and the best results reached up to now are creating bases for further applications.
Behavior studies of thermoplastic polymers during non-isothermal crystallization are extremely important since most of their properties are influenced by degree of crystallinity and the crystallization process. In general, an approach based on a model-fitting method is used to perform crystallization kinetic studies. Due to their inability to uniquely determine the reaction mode, many studies have used the isoconversional method, where it is not necessary to assume a crystallization model to obtain the kinetic parameters. Therefore, in this work, the influence of acid and octadecylamine functionalized carbon nanotubes (CNTs) in the crystallization kinetic of polyethylene (PE) was studied using an isoconversional method with differential scanning calorimetry (DSC) and polarized optical microscopy (POM). The kinetic parameters and the crystallization model were determined. The incorporation of functionalized and non-functionalized CNTs into PE did not change the Johnson-Mehl-Avrami crystallization model. However, the CNTs increased the crystallization temperature and reduced the activation energy for crystallization. In addition, the Avrami coefficient values were lower for the nanocomposites when compared to pure PE. The incorporation of CNTs accelerated the crystallization of PE, reducing the crystallite sizes and modifying their morphology.
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