Fe-doped ZnO nanocrystals are successfully synthesized and structurally characterized by using x-ray diffraction and transmission electron microscopy. Magnetization measurements on the same system reveal a ferromagnetic to paramagnetic transition temperature above 450 K with a low-temperature transition from the ferromagnetic to the spin-glass state due to canting of the disordered surface spins in the nanoparticle system. Local magnetic probes like electron paramagnetic resonance and Mössbauer spectroscopy indicate the presence of Fe in both valence states Fe 2+ and Fe 3+ . We argue that the presence of Fe 3+ is due to possible hole doping in the system by cation ͑Zn͒ vacancies. In a subsequent ab initio electronic structure calculation, the effects of defects ͑e.g., O and Zn vacancies͒ on the nature and origin of ferromagnetism are investigated for the Fe-doped ZnO system. Electronic structure calculations suggest hole doping ͑Zn vacancy͒ to be more effective to stabilize ferromagnetism in Fe-doped ZnO and our results are consistent with the experimental signature of hole doping in ferromagnetic Fe-doped ZnO samples.

No abstract

We report the synthesis of nominal 2 and 5 at.% Mn-doped ZnO nanocrystalline particles by a co-precipitation method. Rietveld refinement of x-ray diffraction data revealed that Mn-doped ZnO crystallizes in the monophasic wurtzite structure and the unit cell volume increases with increasing Mn concentration. DC magnetization measurements showed ferromagnetic ordering above room temperature with Hc∼150 Oe for nominal 2 at.% Mn-doped ZnO nanoparticles annealed at 675 K. A distinct ferromagnetic resonance (FMR) signal was observed in the EPR spectra of the 2 at.% Mn-doped ZnO nanoparticles annealed at 675 K. EPR measurements were used to estimate the number of spins participating in ferromagnetic ordering. Of the total Mn present in the 2 at.% Mn ZnO lattice, 25% of the Mn2+ ions were responsible for ferromagnetic ordering, whereas nearly 5% of the Mn2+ ions remained uncoupled (isolated spins). A well resolved EPR spectrum of 5% Mn-doped ZnO samples annealed at 875–1275 K (g = 2.007, A = 80 G, D = 210 G and E = 15 G) confirmed that Mn was substitutionally incorporated into the ZnO lattice as Mn2+. On increasing the temperature of annealing beyond 1075 K an impurity phase emerges in both the 2 and 5 at.% Mn-doped ZnO samples, which has been identified as a variant of (Zn1−XMn(II)X)Mn(III)2O4 with Tc∼15 K. Our results indicate that the observed room temperature ferromagnetism in Mn-doped ZnO can be attributed to the substitutional incorporation of Mn at Zn-sites rather than due to the formation of any metastable secondary phases.

No abstract

A new Cu(II) complex of an asymmetrically dicondensed Schiff base (HL = N-(2-hydroxyacetophenylidene)-N'-salicylidene-1,3-propanediamine) derived from 1,3-propanediamine, salicylaldehyde, and o-hydroxyacetophenone has been synthesized. Using this complex, [CuL] (1), as a metalloligand, two new trinuclear Cu-Mn complexes, [(CuL)Mn(N)(HO)](ClO)·HO (2) and [(CuL)Mn(NCS)] (3), have been prepared. Single-crystal structural analyses reveal that complexes 2 and 3 both have the same bent trinuclear {(CuL)Mn} structural unit in which two terminal bidentate square-planar (CuL) units are chelated to the central octahedral Mn(II) ion. This structural similarity is also evident from the variable-temperature magnetic susceptibility measurements, which suggest that compounds 2 and 3 are both antiferromagnetically coupled with comparable exchange coupling constants (-21.8 and -22.3 cm, respectively). The only difference between 2 and 3 lies in the coordination around the central Mn(II) ion; in 3, two SCN groups are coordinated to the Mn(II), leaving a neutral complex, but in 2, one N group and one HO molecule are coordinated to give a positively charged species. The presence of such a labile HO coligand makes 2 catalytically active in mimicking two well-known polynuclear copper proteins, catecholase and phenoxazinone synthase. The turnover numbers (k) for the aerial oxidation of 3,5-di-tert-butylcatechol and o-aminophenol are 1118 and 6581 h, respectively, values which reflect the facility of the heterometallic catalyst in terms of both efficiency and catalytic promiscuity for aerial dioxygen activation. The mechanisms of these biomimetic oxidase reactions are proposed for the first time involving any heterometallic catalyst on the basis of mass spectral analysis, EPR spectroscopy, and cyclic voltammetry. The evidence of the intermediates indicates possible heterometallic cooperative activity where the substrates bind to a Mn(II) center and Cu(II) plays the role of an electron carrier for transformation of the phenolic substrates to their respective products with the reduction of aerial dioxygen.

Photoluminescence in the blue and green regions is observed for the first time in nanocrystals of Nd2Zr2O7 synthesized by gel combustion method. This emission is attributed to the presence of oxygen vacancies.

We report the preparation, characterization, and magnetic properties of highly crystalline colloidal Fe-doped indium oxide nanoparticles. The nanoparticles have been prepared in high yields by simple one-pot thermal decomposition of indium and iron precursors in hexadecylamine and can be easily dispersed in solvents like chloroform and toluene. Detailed X-ray diffraction, microstructure, and Raman studies reveal that the nanoparticles are single phase cubic bixbyite structure without any parasitic secondary phases. DC magnetization studies as a function of temperature and field indicate that nanoparticles are weakly ferromagnetic at room temperature (RT). This observation is further confirmed by the electron paramagnetic resonance spectra of the samples, which show a distinct ferromagnetic resonance signal at RT.

Eu(3+) co-doped Y(2)O(3):Tb nanoparticles were prepared by the combustion method and characterized for their structural and luminescence properties as a function of annealing temperatures and relative concentration of Eu(3+) and Tb(3+) ions. For Y(2)O(3):Eu,Tb nanoparticles annealed at 600 and 1200 °C, variation in the relative intensity of excitation transitions between the (7)F(6) ground state and low spin and high spin 4f(7)5d(1) excited states of Tb(3+) is explained due to the combined effect of distortion around Y(3+)/Tb(3+) in YO(6)/TbO(6) polyhedra and the size of the nanoparticles. Increase in relative intensity of the 285 nm peak (spin-allowed transition denoted as peak B) with respect to the 310 nm peak (spin-forbidden transition denoted as peak A) with decrease of Tb(3+) concentration in the Y(2)O(3):Eu,Tb nanoparticles heated at 1200 °C is explained based on two competing effects, namely energy transfer from Tb(3+) to Eu(3+) ions and quenching among the Tb(3+) ions. Back energy transfer from Tb(3+) to Eu(3+) in these nanoparticles is found to be very poor.