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The surface of a solid dielectric insulator becomes electrically charged when subjected to a high-voltage stress in vacuum. A method for calculating the surface flashover voltage based on the assumption that the discharge occurs in a layer of desorbed gases from the insulator surface is proposed. The electric field strength required to cause surface flashover is calculated by taking into account the secondary electron emission characteristics of the dielectric material. The dependence of the surface flashover field on the insulating material is deduced. A dependence of the flashover voltage on the insulator length to a power law of 0.5 is theoretically predicted. The calculated surface flashover voltage is compared with the previously reported measurements and good agreement is obtained.

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The production of ozone was investigated using a dielectric barrier discharge in oxygen, and employing short-duration pulsed power. The dependence of the ozone concentration (parts per million, ppm) and ozone production yield (g(O3)lkWh) on the peak pulsed voltage (17.5 to 57.9 kV) and the pulse repetition rate (25 to 400 pulsesls, pps) was investigated. In the present study, the following parameters were kept constant: a pressure of 1.01~10~ Pa, a temperature of 26 k 4T, a gas flow rate of 3.0 llmin and a gaseous gap length of 11 mm. A concentric coaxial cylindrical reactor was used. A spiral copper wire (1 mm in diameter) was wound on a polyvinylchloride (PVC) cylindrical configuration (26 mm in diameter) and placed centrally in a concentric coaxial electrode system with 4 mm thick PVC dielectric layer adjacent to a copper outer electrode of 58 mm in internal diameter. HV and current pulses were provided by a magnetic pulse compressor power source.

The surface flashover of Teflon, plexiglass, quartz, Pyrex glass, Macor glass-ceramic, and sapphire solid insulators has been measured in vacuum (∼10−8 Torr, ∼10−6 Pa) and in atmospheric air using dc, ac (60 Hz), and 1.2/50-μsec lightning impulse voltages. The dependence of the flashover voltage on the following parameters is investigated: (1) spacer material, (2) diameter of the spacer, (3) spacer length, (4) number of spacers stacked in series, (5) air pressure in the range 10−6–105 Pa, (6) electrode material, (7) spark conditioning, and (8) the external resistance in series with the gap. At a fixed insulator length the flashover voltage decreases with increasing spacer diameter. The withstand voltage of spacers stacked in series increases with increasing the number of spacers. The dc flashover voltage of different insulating materials is theoretically calculated in vacuum as a function of the length of the insulator and compared with the experimentally obtained results. Good agreement is obtained.