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Metal−organic frameworks (MOFs) can act as precursors or templates to a myriad of nanostructured materials that are difficult to prepare. In this study, Co-MOF nanorods (NRs) were prepared at room temperature followed by a calcination and hydrothermal sulfurization strategy to transform the MOF into CoS NRs on carbon cloth (CoS/CC). Intriguingly, the resultant 3D sulfide NRs can serve as scaffolds to electrodeposit layered double hydroxides (LDHs) on the surfaces. Through combining the advantages of structure and composition, the as-fabricated CoS@CoNi-LDH/CC exhibits remarkable electrocatalytic activity for the hydrogen evolution reaction (HER). An overpotential of 124 mV is needed to reach a current density of 10 mA cm −2 with a Tafel slope of only 89 mV dec −1 , which is superior to that of pure CoS/CC (141 mV along with 103 mV dec −1 ) and other reported cobaltbased catalysts. Notably, after the chronopotentiometry test for 50 h, the overpotential of CoS@CoNi-LDH/CC increased by 17 mV only.

TitleCoaxial electrospun cellulose-core fluoropolymer-shell fibrous membrane from recycled cigarette filter as separator for high performance lithium-ion battery Permalink https://escholarship.org/uc/item/9gc5x56wJournal ACS Sustainable Chemistry and Engineering, 3(5)

In this study, we successfully prepare SnO(2) nanoparticles inside the pore channels of CMK-3 ordered mesoporous carbon via sonochemical method. The content of SnO(2) is 17 wt % calculated according to the energy-dispersive X-ray spectroscopy (EDS) result. CMK-3 with 17 wt % loading of SnO(2) nanoparticles has a large specific surface area and pore volume. Electrochemical performance demonstrates that the ordered SnO(2)/CMK-3 nanocomposites electrode possesses higher reversible capacity and cycling stability than that of original CMK-3 electrode. Moreover, the ordered SnO(2)/CMK-3 nanocomposites electrode also exhibits high capacity at higher charge/discharge rate. The improved electrochemical performance is attributed to the nanometer-sized SnO(2) formed inside CMK-3 and the large surface area of the mesopores (3.4 nm) in which the SnO(2) nanoparticles are formed.