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Nanocrystalline titanium dioxide has been prepared under ambient pressure and at temperatures close to or approaching room temperature using hydrolysis of titanium tetraisopropoxide in an acidic aqueous solution. A transparent thin layer of nanocrystalline titania has been produced on cotton textiles by a dip-pad-dry-cure process. These TiO 2 coated cotton textiles possess significant photocatalytic self-cleaning properties, such as bactericidal activity, colorant stain decomposition and degradation of red wine and coffee stains. The UV absorption and tearing strength of the TiO 2 coated cotton has also been studied. Self-cleaning cotton may find potential commercialization in the textile industry.

In this study, a new approach to a uv-blocking treatment for cotton fabrics is developed using the sol-gel method. The treatment forms a thin layer of titania on the surface of cotton fibers, and the treated fabrics show much improved protection against UV radiation. with a UPF factor of 50+ or excellent protection according to the Australian/New Zealand standards. The treated fabrics are also tested for washfastness. The results show that the excellent uv protection rating of the treated fabrics can be maintained even after 55 home launderings, indicating a high level of adhesion between the titania layer and the cotton. A bursting strength test of the treated fabrics shows no adverse effect from the treatment.

While energy shortage is always an issue, the impending exhaustion of fossil fuel sources makes it an ever increasingly pressing one.

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Photoelectrochemcial (PEC) properties of TiO2 nanorod arrays (TNRA) have been extensively investigated as they are photostable and cost-effective. However, due to the wide band gap, only the UV part of solar light can be employed by TiO2. To enhance the photoresponse of TNRA in the visible range, carbon dots (C dots) were applied as green sensitizer in this work by investigating the effects of C dot loading and length of TiO2 nanorod on the PEC properties of TNRA/C dot nanocomposites. As the C dot loading increases, the photocurrent density of the nanocomposites was enhanced and reached a maximum when the concentration of the C dots was 0.4 mg/mL. A further increase in the C dot concentration decreased the photocurrent, which might be caused by the surface aggregation of C dots. A compromise existed between charge transport and charge collection as the length of TiO2 nanorod increased. The incident photon to current conversion efficiency (IPCE) of the TNRA/C dot nanocomposites in the visible range was up to 1.2-3.4%. This work can serve as guidance for fabrication of highly efficient photoanode for PEC cells based on C dots.

We successfully prepared transparent and durable superhydrophobic silica‐coating films on cotton substrates at low temperatures. The coatings were produced via cohydrolysis and polycondensation of a hexadecyltrimethoxysilane (HDTMS), tetraethoxyorthosilcate (TEOS), and 3‐glycidyloxypropyltrimethoxysilane (GPTMS) mixture. The hydrophobic properties of the nanocomposite coatings were determined using contact‐angle and water‐gain measurements. The water contact angle for the coated substrates was 141°, whereas, before coating, the contact angle was 0° because of the superhydrophilic nature of cotton. The nanocomposite coating has new applications in daily used materials, especially those with low heat resistance, such as textiles and plastics, and as an environmentally friendly water‐repellent substitute for fluorine compounds.