Developing a feasible and efficient separation membrane for the purification of highly emulsified oily wastewater is of significance but challenging due to the critical limitations of low flux and serious membrane fouling. Herein, a biomimetic and superwettable nanofibrous skin on an electrospun fibrous membrane via a facile strategy of synchronous electrospraying and electrospinning is created. The obtained nanofibrous skin possesses a lotus‐leaf‐like micro/nanostructured surface with intriguing superhydrophilicity and underwater superoleophobicity, which are due to the synergistic effect of the hierarchical roughness and hydrophilic polymeric matrix. The ultrathin, high porosity, sub‐micrometer porous skin layer results in the composite nanofibrous membranes exhibiting superior performances for separating both highly emulsified surfactant‐free and surfactant‐stabilized oil‐in‐water emulsions. An ultrahigh permeation flux of up to 5152 L m−2 h−1 with a separation efficiency of >99.93% is obtained solely under the driving of gravity (≈1 kPa), which was one order of magnitude higher than that of conventional filtration membranes with similar separation properties, showing significant applicability for energy‐saving filtration. Moreover, with the advantage of an excellent antioil fouling property, the membrane exhibits robust reusability for long‐term separation, which is promising for large‐scale oily wastewater remediation.
Porous modification is a general approach to endowing the rigid inorganic thermoelectric (TE) materials with considerable flexibility, however, by which the TE performances are severely sacrificed. Thus, there remains an ongoing struggle against the trade-off between TE properties and flexibility. Herein, we develop a novel strategy to combine BiTe thick film with ubiquitous cellulose fibers (CFs) via an unbalanced magnetron sputtering technique. Owing to the nano-micro hierarchical porous structures and the excellent resistance to crack propagation of the BiTe/CF architectures, the obtained sample with a nominal BiTe deposition thickness of tens of micrometers exhibits excellent mechanically reliable flexibility, of which the bending deformation radius could be as small as a few millimeters. Furthermore, the BiTe/CF with rational internal resistance and tailorable shapes and dimensions are successfully fabricated for practical use in TE devices. Enhanced Seebeck coefficients are observed in the BiTe/CF as compared to the dense BiTe films, and the lattice thermal conductivity is remarkably reduced due to the strong phonon scattering effect. As a result, the TE figure of merit, ZT, is achieved as high as ∼0.38 at 473 K, which competes with the best flexible TEs and can be further improved by optimizing the carrier concentrations. We believe this developed technique not only opens up a new window to engineer flexible TE materials for practical applications but also promotes the robust development of the fields, such as paper-based flexible electronics and thin-film electronics.
Creating a porous membrane to effectively separate the emulsified oil-in-water emulsions with energy-saving property is highly desired but remains a challenge. Herein, a multilayer nanofibrous membrane was developed with the inspiration of the natural architectures of earth for gravity-driven water purification. As a result, the obtained biomimetic multilayer nanofibrous membranes exhibited three individual layers with designed functions; they were the inorganic nanofibrous layer to block the serious intrusion of oil to prevent the destructive fouling of the polymeric matrix; the submicron porous layer with designed honeycomb-like cavities to catch the smaller oil droplets and ensures a satisfactory water permeability; and the high porous fibrous substrate with larger pore size provided a template support and allows water to pass through quickly. Consequently, with the cooperation of these three functional layers, the resultant composite membrane possessed superior anti-oil-fouling property and robust oil-in-water emulsion separation performance with good separation efficiency and competitive permeation flux solely under the drive of gravity. The permeation flux of the membrane for the emulsion was up to 5163 L m h with a separation efficiency of 99.5%. We anticipate that our strategy could provide a facile route for developing a new generation of specific membranes for oily wastewater remediation.
Thin-film thermoelectrics
(TEs) with unique advantages have triggered
great interest in thermal management and energy harvesting technology
for ambient temperature microscale systems. Although they have exhibited
a good prospect, their unsatisfactory performances still seriously
hamper their widespread application. Tailoring the porous structure
has been demonstrated to be a facile strategy to significantly reduce
thermal conductivity and enhance the figure of merit (ZT) of bulk TE materials; however, it is challenging for thin-film
TEs. Here, the nanoporous Bi2Te3 thin films
with faceted pore shapes and various porosities, pore sizes, and pore
intervals are carefully designed and fabricated by evacuating the
over-stoichiometry Te atoms. The dependence of the carrier mobility
and lattice thermal conductivity on the pore characteristics is investigated.
In the case of the pore interval longer than the electron mean free
path, the porous structure greatly reduces the lattice thermal conductivity
without affecting the electrical conductivity obviously. Phonon specular
backscattering that is highly related to the pore characteristics
is suggested to be mainly responsible for thermal conductivity reduction,
resulting in ∼60% enhancement in ZT at room
temperature, that is, from ∼0.42 for the dense film to ∼0.67
for the nanoporous film. The enhanced ZT value is
comparable to that of commercial bulk TEs and can be further improved
by optimizing the carrier concentrations. This work provides a general
approach to fabricate high-performance chalcogenide TE thin-film materials.
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