Summary The reliable protection of personal safety and vehicle service security has aroused the rising attention on battery thermal safety issues. This poses ongoing challenges for battery thermal management (BTM) to improve the safety by constantly learning and adopting advanced technologies from thermal management to thermal safety control. On the basis of electrochemical, mechanical, and thermo‐kinetic characteristics of battery behavior evolution under operational conditions of normal and abnormal, BTM with enhanced safety cannot only guarantee the battery operation performance but also improve thermo‐safety behavior with the heat transfer intensifying method. Additionally, via effective measurements to detect and warn the battery behavior evolution characteristics, the combination of emergency cooling, fire extinguishing, and thermal barrier adopted in BTM with enhanced safety can effectively and sufficiently suppress battery thermal overheating and its propagation. As concluded, the synthesized integration of basic BTM and its safety‐enhanced treatment can ensure the optimal working temperature range and prevent thermal overheating from propagation. Thus, the BTM system with enhanced safety has been a promising research priority. This article provides a comprehensive review on BTM with enhanced safety aiming to promote the battery application with high energy density, security, and cyclic stability served for electrification and intelligentization of automobiles. In addition, the summary of relevant research status and key technology is dedicated to improving BTM thermo‐safe design innovation and collaborative optimization, to fit with the sustainable development needs of the long‐term mechanism of energy conservation and green‐energy vehicles marketization.

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This study reports on the characterization of reporter dye‐loaded block copolymer vesicles (polymersomes) of PS115‐b‐PAA15 (polystyrene‐block‐poly(acrylic acid)) and PEG114‐b‐PLA167 (poly(ethylene glycol)‐block‐poly(lactic acid)) and their drying behavior by fluorescence lifetime imaging microscopy (FLIM). The characteristic changes of the fluorescence decay components of the dye calcein incorporated in the three different local nanoenvironments, namely, the solvated dye, dye associated with the vesicle wall, and dried agglomerated dye, are observed by FLIM during the drying of vesicles. The amplitude ratio R1/2 of the components attributed to the solvated dye in the vesicle interior with a lifetime τ1 ≈ 3.9 ns to the one attributed to calcein associated with the wall with a lifetime τ2 ≈ 1.5 ns is found to decrease exponentially with drying time. The time constants, which are found to depend linearly on the radius of the vesicle, yield by extrapolation to zero vesicle diameter an estimate of the polymersome wall thickness. For PS115‐b‐PAA15 and PEG114‐b‐PLA167 vesicle wall thicknesses r0 of 16 ± 5 nm and 28 ± 4 nm, respectively, are observed, which are in favorable agreement with transmission electron and atomic force microscopy data.

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