To establish an online analytical method towards estrogenic pollutants, a covalent organic porous polymer (COP) was in-situ synthesized on the surface of basalt fibers (BFs) for in-tube solid-phase microextraction (IT-SPME). The extraction tube, obtained via placing the modified BFs into a polyetheretherketone tube, was combined with high-performance liquid chromatography (HPLC) to achieve online IT-SPME-HPLC analysis. The important parameters, including sampling volume, sampling rate, organic solvent content and desorption time, were carefully investigated. Under the optimized conditions, the online analytical method was established for five estrogenic targets, with low limits of detection (0.001–0.005 μg/L), high enrichment factors (1800–2493), wide linear ranges (0.003–20, 0.015–20 μg/L) and satisfactory repeatability. It was successfully applied to detect five estrogens in a wastewater sample and a water sample in a polycarbonate cup. The BFs functionalized with COPs displayed excellent extraction effect for estrogenic pollutants, furthermore it has great potential in sample preparation or other fields.

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Resorcinol-formaldehyde aerogel coating was in situ prepared on the surface of basalt fibers. The aerogel coating is uniformly modified onto basalt fibers, and it is very porous according to the characterization by using scanning electron microscopy. An extraction tube was prepared for in-tube solid-phase microextraction by placing the aerogel-coated basalt fibers into a polyetheretherketone tube. To evaluate the extraction performance toward five estrogenic compounds, the tube was connected with high performance liquid chromatography, the important extraction and desorption conditions were investigated. An online analytical method for detection of estrogens was developed and presented low limits of detection (0.005-0.030 µg/L), wide linear ranges (0.017-20, 0.033-20, and 0.099-20 µg/L), good linearity (r > 0.9990), and satisfactory repeatability (relative standard deviation < 2.7%). The method was successfully applied to detect trace estrogens in real water samples (bottled pure water and bottled mineral water), satisfactory recoveries were ranged from 80 to 125% with two spiking levels of 2 and 6 µg/L. K E Y W O R D Saerogels, estrogens, high performance liquid chromatography, online analysis, solid-phase microextraction

Crop production and water productivity may be impacted by diverse crop rotation and management practices. A field study was conducted from 2017-2020 in the Loess Plateau to evaluate the effects of crop rotation sequences on pre-planting and post-harvest soil water storage (SWS), annualized crop yield, water use, and water productivity. Crops in rotation included oil flax (Linum usitatissimum L.) (F), wheat (Triticum aestivum L.) (W), potato (Solanum tuberosum L.) (P). Twelve 4-year-cycle crop rotation treatments, along with a continuous oil flax treatment as a baseline, were included. The results showed that the average soil water content under the 0-150 cm soil layer in all treatments was increased after one rotation cycle, and the PWFW treatment achieved the highest SWC (17.1%). The average soil water storage (winter fallow season) and evapotranspiration (ETa) (growing season) under different crop rotation sequences were lower than those under continuous oil flax cropping. The ETa of FFFF increased by 28.9, 2.7, 15.3, and 28.4%, compared to average crop rotations in 2017, 2018, 2019, and 2020, respectively. Crop rotation had a significant effect on average annual yield and water use efficiency (WUE), which varied by year and rotation sequence. The crop rotations with the highest grain yield of oil flax were FFWP (2017), WFWP (2018),WPFF (2019) and FWPF (2020); the grain yield of wheat was highest when the two pre-crops (previously cultivated crops) were F-F, and potato yield was highest when the two pre-crops were W-F (except 2018). On average, the WUE of oil flax was 8.6, 38.7, 22.7, and 42.1% lower with FFFF than other diversity crop rotations in 2017, 2018, 2019, and 2020. We found that the WUE was not the largest when the grain yield of oil flax and wheat was highest. The treatments with maximum grain yield and WUE were not consistent. Our findings also revealed that wheat-potato-oil flax or potato-wheat-oil flax rotation could increase oil flax grain yields while wheat-oil flax-potato-oil flax markedly improved oil flax WUE.

As a by-product generated from the pyrolysis of biomass, biochar is extraordinary for improving the soil environment of agricultural fields, improving soil fertility, and promoting nutrient uptake and the utilization of crops. In recent years, breakthroughs in progress have been made regarding the fertility value of biochar and in investigations into the physicochemical properties of soil and into plant nutrient utilization. This review focuses on the physicochemical and biological properties of soil, on soil pollution remediation, on greenhouse gas emissions, and on the effects of biochar on the uptake and utilization of soil nutrients and plant nutrients, as well as on the preparation of biochar, and on biochar produced under different conditions. The results of the relevant studies show that the main characteristics of biochar depend on the biochemical properties and pyrolysis temperature of raw materials, which play an important role in nutrient transport and transformation in the soil. At low temperatures (≤400 ℃), the biochar prepared from manure and waste contains a large amount of nitrogen, which can be used as a nutrient source for plants. In addition, biochar enhances soil fertilizer retention by reducing soil nutrient loss, which in turn promotes nutrient uptake and utilization by crops. By controlling pyrolysis temperature and by optimizing biochar input, one can effectively reduce soil respiration, as well as reduce carbon emissions to achieve the goal of controlling carbon sources and increasing carbon sinks. Therefore, a long-term series of mapping studies on the effects of biochar application on agricultural ecosystems should be conducted, which in turn, it is hoped, will provide a theoretical reference for the physiological and ecological effects of biochar croplands.

A capillary column coated with nanostructured silver coating was fabricated for gas chromatography. The nanostructured silver coating, about 80–120 nm in thickness, was prepared as the stationary phase via silver mirror reaction, and was characterized by SEM and EDS. The column was evaluated using different types of model analytes, including n-alkanes, n-alcohols, benzenes, and Grob mixture. A baseline separation of ten n-alkanes on the silver column (15 m × 0.20 mm i.d.) was achieved within 3.5 min through the main hydrophobic mechanism. A mixture of six n-alcohols, or another mixture containing three butanol isomers and two octanol isomers, was separated well on the column. The column separated some benzenes containing benzene, toluene, ethylbenzene, p-xylene, o-xylene, styrene, benzaldehyde, and benzyl alcohol. A Grob mixture containing seven analytes was also separated successfully. Based on a multiple retention mechanism such as hydrophobic, dipole-dipole, and dipole-induced dipole interactions, the silver column achieved a good separation of twelve different types of compounds within 2.5 min. The column presented satisfactory separation repeatability with relative standard deviation of retention time between 0.073% and 0.591%. The results indicate that the silver column is promising for gas chromatographic separation.

Increasing water shortages and environmental pollution from excess chemical nitrogen fertilizer use necessitate the development of irrigation-nitrogen conservation technology in oilseed flax production. Therefore, a two-year split-plot design experiment (2017–2018) was conducted with three types of irrigation (I) levels (no irrigation (I0), irrigation of 1200 m3 ha−1 (I1200), and 1800 m3 ha−1 (I1800)) as the main plot and three nitrogen (N) application rates (0 (N0), 60 (N60) and 120 (N120) kg N ha−1) as the subplot in Northwest China to determine the effects of irrigation and N rates on oilseed flax grain yield, yield components, water-use efficiency (WUE), and N partial factor productivity (NPFP). The results show that I1800 optimized the farmland water storage and water storage efficiency (WSE), which gave rise to greater above-ground biomass. Under I1800, the effective capsule (EC) number increased significantly with increasing irrigation amounts, which increased significantly with increasing nitrogen application rate (0–120 kg ha−1). Both irrigation and nitrogen indirectly affect GY by affecting EC; the highest grain yield was observed at the I1800N60 treatment, which increased by 69.04% and 22.80% in 2017 and 2018 compared with the I0N0 treatment, respectively. As a result, both irrigation and N affect grain yield by affecting soil water status, improving above-ground biomass, and finally affecting yield components. In addition, I1800N60 also obtained a higher WUE and the highest NPFP due to a higher grain yield and a lower N application rate. Hence, our study recommends that irrigation with 1800 m3 ha−1 coupled with 60 kg N ha−1 could be a promising strategy for synergistically improving oilseed flax WUE, grain yield and yield components within this semi-arid region.

Organic fertilizers are an important source of nutrients for improving farmland fertility. To explore high-yield, efficient and green production technology for oilseed flax in dryland agricultural areas, a field split plot experiment was conducted in the semi-arid area of the Loess Plateau in northwest China from April to August in 2020 and 2021. The study compared and analyzed the effects of different nutrient sources and their application rates on water consumption characteristics, grain yield and water use efficiency of oilseed flax. The main plots were fertilizer types (sheep manure, chicken manure and chemical fertilizer), while the subplots were fertilizer application rates (sheep manure: S1-12,500 kg·hm−2 and S2-25,000 kg·hm−2; chicken manure: C1-5800 kg·hm−2 and C2-11,600 kg·hm−2; chemical fertilizer: F1-N 112.5 kg·hm−2, P 75 kg·hm−2, K 67.5 kg·hm−2 and F2-N 225 kg·hm−2, P2O5 150 kg·hm−2, K2O 135 kg·hm−2). The results showed that compared with chemical fertilizers, organic fertilizers significantly increased the soil water storage capacity of the 0–160 cm soil layer during the whole growth period of oilseed flax and significantly reduced water consumption. During two growing seasons, the application of 25,000 kg·hm−2 sheep manure significantly reduced water consumption during the seedling-bud period and green fruit period-maturity period of oilseed flax by 16.13% and 23.19% compared with CK, respectively. Thousand-grain weight, yield and water use efficiency were significantly increased by 14.70%, 48.32% and 61.29%, respectively. These results indicate that the application of 25,000 kg·hm−2 sheep manure can significantly increase soil water storage capacity of the 0–160 cm soil layer, reduce water consumption during the whole growth period of oilseed flax and thus improve grain yield and water use efficiency of oilseed flax. It is a suitable fertilization technology for the high-yield, efficient and green production of oilseed flax in the semi-arid areas of northwest Loess Plateau.