Low-cost X-ray detectors with high performance, durability, and flexibility, are required for a wide range of applications in several fields, such as medical (diagnostic radiology, imaging, etc.), nondestructive testing (radioscopic inspections, radiography testing, etc.), security and defence (baggage/body scanning systems, paper mail, etc.), nuclear and radiation industries (nuclear power plants, research reactors, users of nuclear gauges, etc.), and research and development. [1] X-ray detection using semiconductors, based on the direct generation of electrical signals by X-rays (i.e., direct scheme), offers better spatial resolution and a simpler route than indirect schemes, in which X-rays are converted into photons by scintillating phosphors before detection by photodiode arrays. [2] Currently, the conventional materials used for direct conversion of X-rays include stabilized amorphous Se (α-Se), PbI 2 , HgI 2 , CdTe, and CdZnTe. [3] Metal halide perovskites represent a family of the most promising materials for fascinating photovoltaic and photodetector applications due to their unique optoelectronic properties and much needed simple and low-cost fabrication process. The high atomic number (Z) of their constituents and significantly higher carrier mobility also make perovskite semiconductors suitable for the detection of ionizing radiation. By taking advantage of that, the direct detection of soft-X-ray-induced photocurrent is demonstrated in both rigid and flexible detectors based on all-inorganic halide perovskite quantum dots (QDs) synthesized via a solution process. Utilizing a synchrotron soft-X-ray beamline, high sensitivities of up to 1450 µC Gy air −1 cm −2 are achieved under an X-ray dose rate of 0.0172 mGy air s −1 with only 0.1 V bias voltage, which is about 70-fold more sensitive than conventional α-Se devices. Furthermore, the perovskite film is printed homogeneously on various substrates by the inexpensive inkjet printing method to demonstrate large-scale fabrication of arrays of multichannel detectors. These results suggest that the perovskite QDs are ideal candidates for the detection of soft X-rays and for large-area flat or flexible panels with tremendous application potential in multidimensional and different architectures imaging technologies.
In article number 1901644, Babar Shabbir, Yupeng Zhang, Qiaoliang Bao, and co‐workers utilize inexpensive inkjet printing to homogeneously print a perovskite film consisting of all‐inorganic halide perovskite quantum dots on various substrates, which they further develop into an X‐ray detector. This type of detector is an ideal candidate for applications in soft/hard X‐ray detection and large‐area flat/flexible imaging technologies.
A crucial result in quantum chaos, which has been established for a long time, is that the spectral properties of classically integrable systems generically are described by Poisson statistics whereas those of time-reversal symmetric, classically chaotic systems coincide with those of random matrices from the Gaussian orthogonal ensemble (GOE). Does this result hold for two-dimensional Dirac material systems? To address this fundamental question, we investigate the spectral properties in a representative class of graphene billiards with shapes of classically integrable circular-sector billiards. Naively one may expect to observe Poisson statistics, which is indeed true for energies close to the band edges where the quasiparticle obeys the Schrödinger equation. However, for energies near the Dirac point, where the quasiparticles behave like massless Dirac fermions, Poisson statistics is extremely rare in the sense that it emerges only under quite strict symmetry constraints on the straight boundary parts of the sector. An arbitrarily small amount of imperfection of the boundary results in GOE statistics. This implies that, for circular sector confinements with arbitrary angle, the spectral properties will generically be GOE. These results are corroborated by extensive numerical computation. Furthermore, we provide a physical understanding for our results.
Recently, vacancy-related spin defects in silicon carbide (SiC) have been demonstrated to be potentially suitable for versatile quantum interface building and scalable quantum network construction. Significant efforts have been undertaken to identify spin systems in SiC and to extend their quantum capabilities using large-scale growth and advanced nanofabrication methods. Here we demonstrated a type of spin defect in the 4H polytype of SiC generated via hydrogen ion implantation with high-temperature post-annealing, which is different from any known defects. These spin defects can be optically addressed and coherently controlled even at room temperature, and their fluorescence spectrum and optically detected magnetic resonance spectra are different from those of any previously discovered defects. Moreover, the generation of these defects can be well controlled by optimizing the annealing temperature after implantation. These defects demonstrate high thermal stability with coherently controlled electron spins, facilitating their application in quantum sensing and masers under harsh conditions.
Electron spin resonance (ESR) spectroscopy has broad applications in physics, chemistry, and biology. As a complementary tool, zero-field ESR (ZF-ESR) spectroscopy has been proposed for decades and shown its own benefits for investigating the electron fine and hyperfine interaction. However, the ZF-ESR method has been rarely used due to the low sensitivity and the requirement of much larger samples than conventional ESR. In this work, we present a method for deploying ZF-ESR spectroscopy at the nanoscale by using a highly sensitive quantum sensor, the nitrogen vacancy center in diamond. We also measure the nanoscale ZF-ESR spectrum of a few P1 centers in diamond, and show that the hyperfine coupling constant can be directly extracted from the spectrum. This method opens the door to practical applications of ZF-ESR spectroscopy, such as investigation of the structure and polarity information in spin-modified organic and biological systems.
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