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Phenomena analogous to ground state quantum phase transitions have recently been noted to occur among states throughout the excitation spectra of certain many-body models. These excited state phase transitions are manifested as simultaneous singularities in the eigenvalue spectrum (including the gap or level density), order parameters, and wave function properties. In this article, the characteristics of excited state quantum phase transitions are investigated. The finite-size scaling behavior is determined at the mean field level. It is found that excited state quantum phase transitions are universal to two-level bosonic and fermionic models with pairing interactions.

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We analyze excited-state quantum phase transitions (ESQPTs) in three schematic (integrable and nonintegrable) models describing a single-mode bosonic field coupled to a collection of atoms. It is shown that the presence of the ESQPT in these models affects the quantum relaxation processes following an abrupt quench in the control parameter. Clear-cut evidence of the ESQPT effects is presented in integrable models, while in a nonintegrable model the evidence is blurred due to chaotic behavior of the system in the region around the critical energy.

We study the critical behavior of excited states and its relation to order and chaos in the Jaynes-Cummings and Dicke models of quantum optics. We show that both models exhibit a chain of excited-state quantum phase transitions demarcating the upper edge of the superradiant phase. For the Dicke model, the signatures of criticality in excited states are blurred by the onset of quantum chaos. We show that the emergence of quantum chaos is caused by the precursors of the excited-state quantum phase transition.

We review the effects of excited-state quantum phase transitions (ESQPTs) in interacting many-body systems with finite numbers of collective degrees of freedom. We classify typical ESQPT signatures in the spectra of energy eigenstates with respect to the underlying classical dynamics and outline a variety of quantum systems in which they occur. We describe thermodynamic and dynamic consequences of ESQPTs, like those in microcanonical thermodynamics, quantum quench dynamics, and in the response to nearly adiabatic or periodic driving. We hint at some generalizations of the ESQPT concept in periodic lattices and in resonant tunneling systems.

We show that the second-order phase transition between spherical and deformed shapes of atomic nuclei is an isolated point following from the Landau theory of phase transitions. This point can occur only at the junction of two or more first-order phase transitions which explains why it is associated with one special type of structure and requires the recently proposed first-order phase transition between prolate and oblate nuclear shapes. Finally, we suggest the first empirical example of a nucleus located at the isolated triple-point.