This paper presents mechanical, microstructural, and physical characterization of glass fiber-reinforced polymer ͑GFRP͒ bars exposed to concrete environment. GFRP bars were embedded in concrete and exposed to tap water at 23, 40, and 50°C to accelerate the effect of the concrete environment. The measured tensile strengths of the bars before and after exposure were considered as a measure of the durability performance of the specimens and were used for long-term properties prediction based on the Arrhenius theory. In addition, Fourier transform infrared spectroscopy, differential scanning calorimetry, and scanning electron microscopy were used to characterize the aging effect on the GFRP reinforcing bars. The results showed that the durability of mortar-wrapped GFRP bars and exposed to tap water was less affected by accelerated aging than the bars exposed to simulated pore-water solution. These results confirmed that the concerns about the durability of GFRP bars in concrete, based on simulated laboratory studies in alkaline solutions, do not properly correspond to the actual service life in concrete environments.

The research undertaken during the last two decades has shown that one of the potential solutions to the steel-corrosion-related problems in concrete is the use of fiber-reinforced composite (FRP) reinforcement as a replacement for traditional steel bars. Glass FRP (GFRP) reinforcement is gaining more popularity in construction of bridges and in other concrete structures because of its low cost compared to Carbon FRP reinforcement. The durability of these materials, especially under severe environmental conditions, is now recognized as the most critical topic of research. The lack of data on durability of the GFRP reinforcements is a major obstacle to their acceptance on a broader scale in civil engineering. This paper summarizes the most significant research work published on the durability of FRP bars in the past two decades. A comprehensive review of the literature on the durability of FRP bars indicates a significant increase in the number of studies in this area in the last decade. The durability tests conducted by the authors and others on the latest generation of GFRP bars subjected to stresses higher than the design limits, combined with aggressive mediums at elevated temperatures, have concluded that the strength reduction factors adopted by current codes and guidelines are conservative. These factors were based on limited test results that were carried out on the early generations of the GFRP products, which have now substantially changed.

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Fiber-reinforced polymer ͑FRP͒ composites are increasingly being used in civil engineering applications due to their numerous advantages. Moreover, some environmental conditions can potentially enhance their long-term durability. Therefore, the study of their long-term behavior is crucial to ensure their durability. To perform durability study in a reasonable time limit, accelerating factor, such as high temperature, is generally used. However, the use of very high temperature of conditioning could amplify the reduction of the properties leading to conservative prediction of long-term properties. The present paper attempts to clarify the effects of high temperatures on the mechanical and barrier properties ͑moisture absorption͒ of GFRP's internal reinforcement, by presenting some experimental results and conclusions of laboratory accelerated studies.

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Amino units were grafted onto the surface of small particle size alumina by reaction with 3‐aminopropyltriethoxysilane. Atactic polystyrene (PS) was sulfonated (1‐14 mol% sulfonation) and mixed with both modified and unmodified alumina at filler loadings varying from 30 to 80 wt %. The resulting composites were characterized by differential scanning calorimetry, Fourier transform infra‐red spectroscopy, and dynamic mechanical spectroscopy in the glass transition region at a frequency of 1 Hz. Whereas mixtures of unsulfonated PS with either filler showed essentially no change in Tg with filler content, sulfonated PS saw its Tg increase as a function of filler loading at a rate which was greater following modification of the alumina. At a fixed filler loading of 30 wt%, the composite rubbery plateau modulus was found to increase with copolymer sulfonic acid content, while the loss tangent maximum corresponding to the glass transition broadened and decreased. These observations were interpreted as a manifestation of the decrease in polymer mobility brought upon by the formation of noncovalent crosslinks resulting from the proton transfer from the sulfonic acid units on the polymer to hydroxyl and/or amino units at the surface of the filler. © 1994 John Wiley & Sons, Inc.

One of the most important fields of research dealing with the use of carbon-, basalt-, and glass-fiber composites in the civil construction industry is their behavior under various chemical exposure conditions. Fiber-reinforced-polymer composites used as internal and external reinforcement in various structural applications can be subjected to widely differing pH situations. This study investigated the chemical durability of various carbon, basalt and glass fibers. The fibers were immersed in four types of solutions with acid, saline, alkaline, and deionized-water conditioning schemes. The fiber mass loss and surface damage along with changes due to chemical reactions were observed through weight-loss measurements and scanning electron microscopy. A criterion was developed to characterize the performance of fibers as very good, good, fair, and poor. This methodology can also be used by manufacturers as a quick quality-control tool for evaluating the chemical resistance of different fibers prior to large-volume production. The results reveal that the carbon fibers exhibited higher chemical resistance than the basalt and glass fibers based on weight loss and evidence of chemical reactions. Moreover, the determination of the fiber chemical composition before and after conditioning in acid and alkaline solutions clearly shows that the E-glass fibers, which are known to contain boron, were very sensitive to chemical corrosion. The ECR-glass fibers showed excellent chemical durability, even better than the basalt fibers.