In this research, Ni/Al layered double hydroxide (LDH) was modified by using co-precipitation method to generate Ni/Al-graphite (Ni/Al-GF) and Ni/Al-biochar (Ni/Al-BC). The adsorbents were applied to remove Congo Red from aqueous solution. The obtained samples were characterized by using XRD, FTIR, BET and TG-DTA. The XRD diffraction pattern of Ni/Al LDH, Ni/Al-GF, and Ni/Al-BC presented the formation of composite with decreasing crystallinity. The surface area modified LDHs was higher than the pristine materials, which was obtained 15.106 m2/g, 21.595 m2/g and 438.942 m2/g for Ni/Al-LDH, Ni/Al-GF, Ni/Al-BC respectively. The adsorption of Congo Red on the materials was tested at diferent parameters and the results exhibited that Congo Red adsorption on LDHs were pseudo-first-order (PFO) kinetic, spontaneous, endothermic and followed Langmuir model. The adsorbents removed Congo Red by high performance stability with adsorption capacity was 116.297 mg/g for Ni/Al-GF and 312.500 mg/g for Ni/Al-BC. These adsorption capacity was higher than the pristine LDH (61.728 mg/g). The regeneration process which carried out for five cycles showed that Ni/Al-GF and Ni/Al-BC have stable structures as reuse adsorbents for Congo Red from aqueous solution.
Innovative modification of Cu-Al/C composites was synthesized by coprecipitation method at pH 10 and added biochar (BC) and graphite (GF) to form Cu-Al/BC and Cu-Al/GF composites. Pristine and composites were characterized by XRD, FT-IR, Thermalgravimetric, and surface area using the BET method. The XRD diffraction and FTIR spectrum of Cu-Al/BC and Cu-Al/GF showed that the composite material from LDH, biochar, and graphite was successfully prepared. Modified LDH were surface area higher than the pristine, which obtained 200.90 m2/g and 18.83 m2/g for Cu-Al/BC and Cu-Al/GF respectively. Cu-Al/BC and Cu-Al/GF were tested for selectivity on several anionic dyes, it was known that procion red (PR) dye was more easily adsorbed than other anionic dyes. Materials were applied as adsorbents of procion red (PR) dye. The advantages of composites were evaluated by the regeneration process of adsorbent on PR. The result of composite toward PR re-adsorption process showed that Cu-Al/BC and Cu-Al/GF had structural stability higher than starting materials until five cycles process. Furthermore, materials were applied as adsorbents of procion red (PR) dye. The maximum adsorption capacity obtained was 93.458 mg/g for Cu-Al/BC and 49.505 mg/g for Cu-Al/GF. Both innovative modified composites have shown effective adsorbents to the removal of PR from an aqueous solution.
In this study, chitosan was extracted from shrimp shells by demineralization and deproteination processes. The extracted chitosan was used to modify the layered double hydroxide and used as an adsorbent for the removal of congo red from aqueous solutions. Composites were successfully synthesized using M2+/Al (M2+ = Zn, Mg, Ni) and chitosan (CH) and the samples obtained were characterized using XRD and FTIR. The X-ray diffraction (XRD) pattern appeared at the layered double hydroxide peak of 2? = 11.63°; 23.00°; 35.16°; and 61.59° and chitosan at 2? = 7.93° and 19.35. The composite appearing in the layered double hydroxide and chitosan indicated that the composite material has been successfully synthesized. The XRD diffraction patterns of Zn/Al-CH, Ni/Al-CH, and Mg/Al-CH showed low crystallinity. The Fourier Transform Infrared (FTIR) spectra verifying absorption spectrum showed the presence of two bands at 3448 cm-1, 1382cm-1 characteristic to both chitosan and LDH. Adsorption of Congo Red (CR) followed the pseudo-second-order and Langmuir isotherm models. The adsorption capacities of Zn/Al-CH, Ni/Al-CH, and Mg/Al-CH were 181.818 mg/g, 227.273 mg/g, and 344.828 mg/g, respectively. The layered double hydroxide-chitosan composite adsorption was endothermically characterized by positive enthalpy and entropy values. On the other hand, the adsorption spontaneously was characterized by a negative Gibbs free energy value. The composites in this study were formed from LDH modified from chitosan extracted from shrimp shells to form Zn/Al-CH, Ni/Al-CH, and Mg/Al-CH. The results of the characterization showed a number of characteristics that resembled the constituent materials in the form of LDH and chitosan. After being applied as an adsorbent to absorb Congo red dye, it then showed the most effective results using Mg/Al-CH adsorbent with an adsorption capacity of 344.828 mg/g.
IntroductionThe presence of hazardous synthetic dyes in waste water released from industrial process such as cosmetic, textile, leather, painting, food, and drug industries is serious problem due to not only human health but also aquatic ecosystem [1]. Synthetic dyes are very toxic and carcinogenic due to difficult to degrade and stable under light and oxidation process, thus removal of dyes from wastewater is crucial [2]. Treatment to remove or to reduce concentration of dyes from wastewater has been
Modification of Mg/Al-LDH intercalated metal oxide (Mg/Al-Ni) was successfully formed by the coprecipitation method at pH 10, which is indicated by the XRD diffraction, FTIR spectrum, and BET analysis. Mg/Al-LDH increased surface area after intercalated Ni from 8.621 m2/g to 9.821 m2/g and improved performance in process regeneration which can be used in the three cycles. Mg/Al-LDH after intercalated metal oxide (Ni) increases adsorption capacity of is 69.930 mg/g to 71.429 mg/g for methyl orange (MO) and 77.519 mg/g to 98.039 mg/g for methyl red (MR). Equilibrium time on the adsorption process occurred at 90 minutes with adsorption kinetics followed pseudo-second-order (PSO). Thermodynamic parameters indicate that the adsorption process is spontaneous and endothermic with the physical adsorption process.
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