A family of threshold parameters which probe the stability of chiral predictions is considered. The relevant criteria for the choice of threshold parameters are discussed. Sum rules for these quantities are derived from dispersion relations and evaluated from effective range formulae. Good agreement with two-loop chiral estimates for many of these quantities is found and interesting discrepancies are discussed.Keywords: Sum rules, ππ scattering, chiral perturbation theory PACS: 12.39.Fe, 13.75.Lb, 11.55.Fv, 25.80.Dj 1. Dispersion relations for ππ scattering amplitudes with two subtractions have been rigorously established in axiomatic field theory [1]. It is convenient to consider dispersion relations for s−channel amplitudes of definite iso-spin, T I s (s, t, u), I = 0, 1, 2, where s, t, u are the Mandelstam variables.Furthermore, each of the amplitudes may be written down in terms of a unique function as T 0 s (s, t, u) = 3A(s, t, u) + A(t, u, s) + A(u, s, t), T 1 s (s, t, u) = A(t, u, s) − A(u, s, t), T 2 s (s, t, u) = A(t, u, s) + A(u, s, t). Unitarity, analyticity and crossing symmetry have been used extensively to study this fundamental process of elementary particle physics. Introducing a partial wave expansion for these amplitudes via T I s (s, t, u) = 32πΣ(2l+1)f I l (s)P l ((t−u)/(s−4)), elastic unitarity implies above threshold and below the four-pion threshold that the partial wave amplitudes may be described in terms of the phase shifts δ I l (s) by f I l (s) = s/(s − 4) exp(iδ I l (s)) sin δ I l (s), where we have set the pion mass (m π = 139.6MeV) to unity. Note the threshold expansion this amplitude has now been computed to one-loop [7] and even two-loop order [9,10].) Furthermore this implies that the only non-vanishing threshold parameters are a 0 0 = 7/(32πF 2 π ), a 2 0 = −1/(16πF 2 π ),It is important to note the well known result that the set of functions:, where α and β are arbitrary real constants, verifies dispersion relations with two subtractions and vanishing absorptive parts. The Weinberg amplitude is a special case of this general linear amplitude, with α = β = 1. It may be noted that a generalized version of chiral perturbation theory that is motivated by considerations of a small quark condensate in the QCD vacuum allows α to vary over a range between unity and as much as three, and reorganizes the chiral power counting [11]. In this discussion we confine ourselves to the more predictive standard chiral perturbation theory with α = 1 for much of our discussion.Dispersion relations with two subtractions have been used to write down sum rules for (combinations) of some of these threshold parameters, for example the Wanders sum rules which maybe written down as:where σ I (ν) ≡ (4π/ ν(ν + 1)) · (2l + 1)Im f I l (ν) are the cross-sections. The Weinberg predictions for the quantities involved in these sum rules obey these relations identically with all the cross-sections set to zero, since the original amplitude obeys dispersion relations with vanishing absorptive parts. Furt...