In continuous fiber-reinforced thermoplastics, the macroscopic failure mode in transverse long-term failure is dominated by a brittle crack-growth mechanism. Neat thermoplastic matrices, on the other hand, generally display also a plasticity-controlled mechanism in long-term loading at elevated stress levels and/or temperature. This failure mechanism requires a different approach to lifetime prediction than crack growth; hence, it is important to identify it in the long-term performance of composites. In this study, we demonstrate the presence of the plasticity-controlled failure mechanism in long-term failure of transversely loaded unidirectional (UD) thermoplastic composites made of glass/iPP, carbon/PEEK and carbon/PEKK. The main method used is to compare the lifetime in cyclic loading to that in static loading at the same level of maximum stress, where an increase in lifetime is characteristic for plasticity controlled failure, and, vice versa, a decrease is indicative for fatigue crack growth. In addition, the applicability of a lifetime prediction method common to plasticity-controlled failure of neat thermoplastics is evaluated for the composites investigated. The results of this study indicate that the plasticity-controlled failure was present in composites, although the extent to which the effects are present varied depending on the materials investigated. Glass/iPP showed the most explicit evidence of the plasticity-controlled failure over the entire load range experimentally covered. Its long-term failure was delayed with a decrease in the stress ratio and lifetime was predicted well using the principles of plasticity-controlled failure.
Herein, temperature‐dependent long‐term behavior of polypropylene and its transversely loaded unidirectional glass fiber reinforced composite is investigated and a lifetime prediction method is proposed, which is based on the observed long‐term failure mechanisms. Furthermore, the effect of cooling rate during processing on the time‐dependent behavior is addressed. The composite is revealed to exhibit multiple molecular deformation mechanisms, similar to neat polypropylene, which is modeled using the Ree–Eyring approach. Failure kinetics under constant‐strain‐rate and creep tests are found to be identical and switching from creep to cyclic loading decelerates the failure, which are signs of plasticity‐controlled failure. Hence, lifetime is predicted well by using a lifetime prediction methodology for the plasticity‐controlled failure which combines the Ree–Eyring approach and the concept of critical strain. A change in the cooling rate alters the deformation and failure kinetics: lower cooling rates promote embrittlement.
In the co-bonding of thermoset and thermoplastic polymers, the interdiffusion of the polymers results in the formation of an interphase between them. Understanding the factors influencing the interdiffusion and the resulting interphase is crucial in order to optimize the mechanical performance of the bond. Herein, for the first time, the effect of the initiator concentration of the thermoset resin-initiator mixture on the interphase thickness of co-bonded thermoset-thermoplastic polymers is investigated. The dependence of the gelation time on the initiator concentration is determined by rheometer measurements. Differential scanning calorimetry measurements are carried out to determine the speed of cure. To co-bond the polymers, pieces of already-manufactured thermoplastic plates are embedded in a resin-initiator mixture. The interphase thickness of the co-bonded polymers is measured with an optical microscope. The results of this study show that the gelation time decreases as the initiator concentration increases. This decrease leads to a significant reduction in both interphase thickness and diffusivity. For instance, increasing the initiator/resin weight ratio from 1% to 3% reduces the gelation time by 74% and the interphase thickness by 63%.
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