Multiferroic heterostructures of Fe3O4/PZT (lead zirconium titanate), Fe3O4/PMN‐PT (lead magnesium niobate‐lead titanate) and Fe3O4/PZN‐PT (lead zinc niobate‐lead titanate) are prepared by spin‐spray depositing Fe3O4 ferrite film on ferroelectric PZT, PMN‐PT and PZN‐PT substrates at a low temperature of 90 °C. Strong magnetoelectric coupling (ME) and giant microwave tunability are demonstrated by a electrostatic field induced magnetic anisotropic field change in these heterostructures. A high electrostatically tunable ferromagnetic resonance (FMR) field shift up to 600 Oe, corresponding to a large microwave ME coefficient of 67 Oe cm kV−1, is observed in Fe3O4/PMN‐PT heterostructures. A record‐high electrostatically tunable FMR field range of 860 Oe with a linewidth of 330–380 Oe is demonstrated in Fe3O4/PZN‐PT heterostructure, corresponding to a ME coefficient of 108 Oe cm kV−1. Static ME interaction is also investigated and a maximum electric field induced squareness ratio change of 40% is observed in Fe3O4/PZN‐PT. In addition, a new concept that the external magnetic orientation and the electric field cooperate to determine microwave magnetic tunability is brought forth to significantly enhance the microwave tunable range up to 1000 Oe. These low temperature synthesized multiferroic heterostructures exhibiting giant electrostatically induced tunable magnetic resonance field at microwave frequencies provide great opportunities for electrostatically tunable microwave multiferroic devices.

Strong magnetoelectric ͑ME͒ coupling was demonstrated in Fe 3 O 4 /PZN-PT ͑lead zinc niobate-lead titanate͒ multiferroic heterostructures obtained through a sputter deposition process. The dependence of the magnetic anisotropy on the electric field ͑E-field͒ is theoretically predicted and experimentally observed by ferromagnetic resonance spectroscopy. A large tunable in-plane magnetic anisotropy of up to 600 Oe, and tunable out-of-plane anisotropy of up to 400 Oe were observed in the Fe 3 O 4 /PZN-PT multiferroic heterostructures, corresponding to a large ME coefficient of 100 Oe cm/ kV in plane and 68 Oe cm/ kV out of plane, which match well with predicted results. In addition, the electric field manipulation of magnetic anisotropy is also demonstrated by the electric fields dependence of magnetic hysteresis loops, showing a large squareness ratio change of 44%. These Fe 3 O 4 /PZN-PT multiferroic heterostructures exhibiting large E-field tunable magnetic properties provide great opportunities for novel electrostatically tunable multiferroic devices.

An energy-efficiency technique for electrically modulating magnetoresistance was demonstrated in multiferroic anisotropic magnetoresistance (AMR) and giant magnetoresistance (GMR) heterostructures. A giant electric field (E-field) induced magnetic anisotropy caused by a strong magnetoelectric coupling was utilized to control the orientation of magnetization and thus dynamically manipulate magnetoresistance in AMR and GMR devices. A multiband tunable AMR field sensor was designed and developed to dramatically enhance the measurement range by 15 times. In addition, two types of E-field determination of GMR in spin-valve structures are studied. The results indicate an energy efficiency approach to controlling magnetoresistance by E-field rather than magnetic field, which shows great potential for novel low power electronic and spintronic devices.

A vibration energy harvester based on a high permeability cantilever beam was demonstrated, which overcomes the limitation of the existing approaches in output power and working bandwidth. Magnetostatic coupling between the vibrating highly permeable beam and bias magnetic field leads to maximized flux change and large induced voltage. The coexistence of magnetostatic and elastic potential energy results in the nonlinear oscillation with wide bandwidth. The harvester showed a maximum power of 74 mW and power density of 1.07 mW/cm3 at 54 Hz under acceleration of 0.57 g (with g=9.8 m/s2), and bandwidth of 10 Hz (or 18.5% of the operating frequency).

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