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This study examines the dynamics of colloid mobilization and leaching from macroporous soil columns by means of laboratory experiments and numerical modeling. On the basis of a previous column study involving high and low water flow rates in structured soil, we designed a novel experiment emphasizing the time‐dependence of the colloid release process. Intact macroporous soil columns were exposed to variable pauses in irrigation (flow interruption for 30 min, 1 d, or 7 d) followed by resumed infiltration. The experiments showed that (i) there was a seemingly unlimited source of in situ colloids even after prolonged leaching and (ii) the peak concentration of colloids in the effluent after the flow interruption increased with increasing length of the preceding pause. The results demonstrated that colloid mobilization is not controlled by hydrodynamic shear induced by the flowing water but is a time‐dependent and possibly diffusion‐limited process. We developed a simple, equivalent macropore model to investigate the hypothesis that colloid release to the flowing water is governed by two diffusion processes, one in a uniform water film lining the macropore and one in the crust of the macropore. The model was capable of reproducing and explaining the characteristic results of our soil column experiments and required no recalibration of exchange process parameters to simulate the particle mobilization after a flow interruption. However, model calibration yielded unexpected results with respect to the size of the diffusion coefficient of the crust and did not warrant accepting the dual diffusion model hypothesis. Using a simpler mass transfer concept to quantify the mobilization of colloids in 21 soil columns, we found mass transfer coefficients to be about 30 times higher in the water film than in the crust.

Movement of particles by water through the soil can be a significant pathway for P transport to surface waters in certain soil types. Our objective was to describe and quantify particulate matter (PM), particulate phosphorus (PP) and dissolved phosphorus (DP) transport tile drains during controlled plot experiments. The results were compared to corresponding studies of natural storm events in the tile‐drained catchment as a whole. Six rain simulations (irrigation 15.3–37 mm) were carried out at two 25 m2 plots on a loamy soil. Tracer chloride concentration in the drainage water peaked within 1 h of the onset of irrigation, thus indicating rapid macropore flow to the drains. PM, PP, and DP concentrations were highest in the initial drainage flow: 63 to 334 mg PM L−1, 0.177 to 0.876 mg PP L−1, and 0.042 to 0.103 mg DP L−1, respectively. Particulate matter and PP loss rates measured for the rapid drainage flow response were in the same range in the plot experiments as for nine precipitation events in the tile‐drained catchment (13.3 ha): 171 to 630 g PM ha−1 mm−1 vs. 141 to 892 g PM ha−1 mm−1, and 0.57 to 1.75 g PP ha−1 mm−1 vs. 0.71 to 5.92 g PP ha−1 mm−1, respectively. Tracer analysis using 137Cs revealed that the PM in the drainage water was derived from the topsoil.

Physical and chemical non‐equilibrium processes may facilitate the transport of pesticides and other chemicals through structured and macroporous soils. For sorbing pesticides, transport associated with a mobile colloidal or particulate phase represents an additional transport mechanismin structured soils that is not well understood. We investigated particle‐facilitated transport of a sorbing pesticide (prochloraz, N‐propyl‐N‐[2‐(2,4,6‐trichlorophenoxy)ethyl]imidazole‐1‐carboxamide) in a 5‐ by 5‐m subsurface‐drained field plot in a structured sandy loam in Denmark. Following pesticide application, three simulated rainfall events during an 8‐d period were monitored in terms of drainage flow rate, content of particulate matter (>0.24 µm), and pesticide concentration in the solution and in the particulate phases in the drainage water. The fraction of pesticide loss to the drain was 0.2% of the applied mass, of which 6% was associated with the particulate phase. Macroporous flow paths appeared to be major routes of pesticide and particle transport. Preferential sorption to particles in the drainage water relative to bulk soil, and possibly also slow desorption from the particles, were assumed to influence the pesticide leaching in the particulate fraction. Based on experimental and reported data, the dual‐porosity model MACRO, modified to account for particle mobilization and transport, could be calibrated to simulate the observations. Sensitive parameters for the particle and pesticide descriptions were identified.