Polymer blending is a well-developed manufacturing process with features of efficient production, ease of processing and good controllability. It can effectively modify and adjust the properties of polymer in order to have greater mechanical, thermal and physical properties, and thus has been commonly used to make functional polymer materials. However, the differences in polarity as well as poor interfacial between each polymer in the blend will promote the difference in polarity between the immiscible and incompatible polymers, and then the blends did not succeed as a good blend. The blending of thermoplastic polyurethane (TPU) with other polymer has been widely study with focus on the improvement of mechanical properties, wear resistance, thermal stability, toughness and other related properties. This review only focuses on the latest studies on blending TPU with other polymer, just in the range of 3 years from 2017 to 2019.
The natural fiber have recently become attractive and been widely used as reinforcement material to replace synthetic fiber as a concern to environmental issue. However, there are some of natural fiber unable to perform well as reinforcement material due to their natural properties. In this research study, the corn stalk fiber was selected as natural fiber reinforced with polybutadiene adipate terephalate (PBAT) to form bio-composite materials. There are two type of PBAT used which are in pellets form and powder form. The objectives of using different type of PBAT are to identify their compatibility with filler and the dispersion of corn stalk fiber in both forms of matrix. Then, the both type of PBAT also compounded with difference loadings of corn stalk fiber. Lastly, their effect on tensile properties and absorption ability were identified. After the test is run, the composite of neat PBAT in powder form shows highest tensile strength and elongation at break but lowest in water absorption percentage compared to others. However, the composition of pellets PBAT with 30wt% of corn stalk fiber shows highest percentage of water absorption compared to others.
Polycaprolactone (PCL) polyol was prepared by a ring opening polymerization of ε-caprolactone initiated by palm kernel oil (PKO) based polyol and 1,6-hexanediol to form a PCL/PKO based polyol. The properties of polyol were varied by their initiator:co-initiator weight ratio. The completion of polyol formation was characterized through Fourier Transformation Infrared (FTIR) spectroscopy. Other parameters such as acid number and hydroxyl number of polyol were also studied to monitor the progress of reaction. FTIR results showed the significant changes particularly for the OH and C=O stretching peaks.
Polyurethane (PU) adhesives were prepared from three different polyols based on polycaprolactone (PCL)/palm kernel oil (PKO) with an aromatic and cycloaliphatic diisocyanate. The adhesives were characterized through Fourier Transformer Infrared (FTIR) spectroscopy in order to ensure the formation of urethane and the completeness of polymer reaction. The effects of NCO/OH ratios and types of diisocyanate on PU adhesive strength were investigated. The adhesive strength of metal to metal bonding was determined by single lap shear joint testing. The correlation between crosslinking of PU network and adhesive strength was also studied by performing swelling tests.
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