No abstract

No abstract

Articles you may be interested inThe intramolecular kinetic isotope effect for the reaction O(3 P)+HD J. Chem. Phys. 92, 7382 (1990); 10.1063/1.458224 Energy dependence, kinetic isotope effects, and thermochemistry of the nearly thermoneutral reactions N+(3 P)+H2(HD,D2)→NH+(ND+)+H(D)Reaction dynamics for O(3 P)+H2, D2, and HD. VI. Comparison of TST and reduced dimensionality quantum and quasiclassical isotope effects with experimentThe reaction of oe P) + H 2 , D 2 , and HD was studied by the flash photolysis-resonance fluorescence method. The rate constants k xy (T) were measured over the temperature ranges 297-471 K for XY = H 2 , 422-472 K for D 2 , and 422-473 K for HD. Above 400 K kHz are in excellent agreement with earlier flow measurements, but below this temperature most of the flow data are systematically lower. A small deviation from the Arrhenius function was observed for kHz at 297 K. Our measurements of kDz are in excellent agreement with the results of Westenberg and deHaas and differ from those Clyne and Thrush. The measured values of k HD equal the arithmetic mean of kHz and kDz within experimental error. A detailed comparison is made between the present results and the CEQB calculations of Bowman, Wagner, Walch, and Dunning and the ICVT/LAG calculations of Garrett and Truhlar. Good overall agreement is obtained with both theories.

Nanofabrication of high aspect ratio (50:1) sub-10nm silicon nanowires using inductively coupled plasma etching J. Vac. Sci. Technol. B 30, 06FF02 (2012); 10.1116/1.4755835Fabrication of ferromagnetic single-electron tunneling devices by utilizing metallic nanowire as hard mask stencil Fabrication of nanometer size photoresist wire patterns with a silver nanocrystal shadowmask

No abstract