The procedures for analyzing pharmaceuticals and personal care products (PPCPs) are typically tedious and expensive and thus, it is necessary to synthesize all available information from previously conducted research. An extensive collection of PPCP data from the published literature was compiled to determine the occurrence, pathways, and the effectiveness of current treatment technologies for the removal of PPCPs in water and wastewater. Approximately 90% of the compiled published papers originated from Asia, Europe, and the North American regions. The incomplete removal of PPCPs in different water and wastewater treatment processes was widely reported, thus resulting in the occurrence of PPCP compounds in various environmental compartments. Caffeine, carbamazepine, diclofenac, ibuprofen, triclosan, and triclocarban were among the most commonly reported compounds detected in water and solid matrices. Trace concentrations of PPCPs were also detected on plants and animal tissues, indicating the bioaccumulative properties of some PPCP compounds. A significant lack of studies regarding the presence of PPCPs in animal and plant samples was identified in the review. Furthermore, there were still knowledge gaps on the ecotoxicity, sub-lethal effects, and effective treatment processes for PPCPs. The knowledge gaps identified in this study can be used to devise a more effective research paradigm and guidelines for PPCP management.
First flush is a phenomenon in stormwater runoff that has been considered a topic of great interest in the field of nonpoint source pollution. Despite several attempts to define the first flush quantitively, the specified characteristics of the phenomenon vary among sources. To address these uncertainties, a bibliometric and comprehensive review on published articles related to first flush was conducted. A corpus of 403 research articles was obtained from the Scopus database, which was then parsed using the CorText Manager for the bibliometric analysis. The study examined quantitative definitions of first flush from various sources; climate and topographic characteristics of monitoring and experimental sites where the studies on first flush were performed; the sample collection methods applied; the first flush values obtained on the studies and how it influenced the nonpoint source pollution in urban watersheds. A network map, two contingency matrices, and a Sankey diagram were created to visualize the relationship of significant keywords related to first flush, as well as their co-occurrences with journals, countries, and years. It was found that the strength of the first flush effect could vary depending on the geographical location of the site, climatic conditions, and the pollutants being analyzed. Therefore, initial rainfall monitoring, runoff sampling, and water quality testing were seen as critical steps in characterizing the first flush in urban catchments. Furthermore, the characterization of first flush was found to be significant to the selection of best management practices and design of low-impact development (LID) technologies for stormwater runoff management and nonpoint source pollution control.
The efficiency of nature-based facilities is mostly evaluated in terms of their pollutant removal capabilities; however, apart from water purification functions, constructed wetlands also perform ecological, cultural, and environmental education functions. A multi-criteria performance index was developed in this study to evaluate the overall efficiency of constructed wetlands. A total of 54 constructed wetlands installed across South Korea were monitored to evaluate the pollutant removal performance of the facilities. A comparison between the conventional pollutant removal-based evaluation and the developed multi-criteria index was also performed to determine the key changes in the results of evaluation when different methods are employed. Among the different types of wetlands studied, hybrid systems were found to be the most effective in terms of pollutant removal due to their complex configurations and functions. Newly constructed treatment wetlands have unstable performance and thus, a stabilization period ranging from two to five years is required to assess the facility’s pollutant removal capabilities. As compared to the conventional pollutant removal-based efficiency evaluation, the comprehensive evaluation method provided a more strategic tool for identifying the facilities’ strengths and weaknesses. Generally, the multi-criteria performance index developed in this inquiry can be utilized as a general tool for evaluating the sustainability of similar nature-based facilities.
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