A B S T R A C TThe non-biodegradability of textile wastewater is mainly due to the presence of synthetic dyes. Resistance to bacterial degradation led to the development of new techniques where solar photocatalysis appears to be the best method for this type of application. methylene blue (MB) degradation was studied in TiO 2 and ZnO aqueous suspension using solar energy in a tubular reactor. This study was conducted to evaluate the performance of the prototype and explore the feasibility of this concept for solar photocatalytic oxidation. The main objective of this work was to compare the efficiency of two types of catalysts, which are titanium dioxide (TiO 2 ) and zinc oxide (ZnO). The use of TiO 2 as a catalyst enables a good degradation of MB which can achieve a disposal rate of 98% after 270 min with a TiO 2 concentration of 0.75 g/L. The same removal rate can be achieved by ZnO but for a much smaller concentration which was 0.025 g/L after 140 min.
The effects of Fe2+ and Fe3+ as TiO2 cocatalysts were studied, and the experimental results showed that Fe3+ was more efficient than Fe2+, which needed an intermediate reaction to produce hydroxyl radicals. TiO2 was modified with the aim of improving its structural, optical, and adsorption properties, thus improving its photocatalytic performance. The light range of the catalyst activation process was expanded, which increased the catalyst's ability to absorb visible light. Consequently, this study exploits solar energy in photocatalysis by Fe ion doping using different methods, including impregnation, photodeposition, solvothermal doping, and hydrothermal doping, and evaluates the influence of each doping method on TiO2 optical properties and photocatalytic activity. Enhancing the catalyst adsorption capacity by morphologically modifying TiO2 nanoparticles into nanotubes using the hydrothermal method increases the catalyst surface area from 55 to 294 m2/g, as shown in the MEB and BET results. The effect of combining morphological changes and Fe3+ doping on TiO2 activity was evaluated. We observed a reduction in the TiO2 band gap from 3.29 to 3.01 eV, absorption edge widening, and an increase in the specific surface area up to 279 m2/g; thus, the synthesized catalyst eliminated Cefixime in 120 min.
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