The results of experimental research into structuration of associated pure liquids and electrolyte solutions in these liquids by NMR spectroscopy are summarized. The influence of self organization on the rate and relay mechanism of proton mobility, chemical kinetics, and thermodynamics is analyzed.Key words: associated liquids, hydrazines, mineral acids, electrolyte solutions, composi tions and structures of labile supramolecular systems, kinetics and mechanism of proton exchange in liquids, disproportionation of perchloric acid, NMR spectroscopy.
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